Bis(diethyldithiocarbamato-S,S')manganese

Base Information

• Chemical Name: Bis(diethyldithiocarbamato-S,S')manganese
• CAS No.: 15685-17-3
• Molecular Formula: C10H20 Mn N2 S4
• Molecular Weight: 351.484
• European Community (EC) Number: 239-769-4
• DSSTox Substance ID: DTXSID70166142
• Nikkaji Number: J248.732B
• Mol file: 15685-17-3.mol

Synonyms:Bis(diethyldithiocarbamato-S,S')manganese;EINECS 239-769-4;15685-17-3;Bis(diethylcarbamodithioato-S,S')manganese;Manganese, bis(diethylcarbamodithioato-S,S')-;C10H20MnN2S4;SCHEMBL2536699;DTXSID70166142;C10-H20-Mn-N2-S4;Manganese, bis(diethyldithiocarbamato)-;Bis(diethylcarbamodithioic acid)manganese(II) salt

Chemical Property of Bis(diethyldithiocarbamato-S,S')manganese

Chemical Property:

• Boiling Point: 176.4°Cat760mmHg
• Flash Point: 60.5°C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 350.988976
• Heavy Atom Count: 17
• Complexity: 73

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)C(=S)[S-].CCN(CC)C(=S)[S-].[Mn+2]

Technology Process of Bis(diethyldithiocarbamato-S,S')manganese

There total 4 articles about Bis(diethyldithiocarbamato-S,S')manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

manganese(II) chloride tetrahydrate + sodium N,N-diethyldithiocarbamate (148-18-5) → bis(diethyldithiocarbamate)manganese(II) (15685-17-3)

Guidance literature:

In ethanol; for 1h;

DOI:10.1021/ja3106253

Reference yield: 71.0%

manganese(II) chloride dihydrate + sodium N,N-diethyldithiocarbamate (148-18-5) → bis(diethyldithiocarbamate)manganese(II) (15685-17-3)

Guidance literature:

In water; for 0.5h; Inert atmosphere; Schlenk technique;

DOI:10.3390/molecules26195954

Reference yield:

manganese(II) nitrate + sodium N,N-diethyldithiocarbamate (148-18-5) → bis(diethyldithiocarbamate)manganese(II) (15685-17-3)

Guidance literature:

With nitric acid; In water; for 0.333333h; pH=8 - 10;

DOI:10.1016/j.saa.2016.06.018

upstream raw materials:

sodium N,N-diethyldithiocarbamate

Downstream raw materials:

bis(N,N-diethyldithiocarbamato)mercury(II)

Refernces

• 1、 Liu, Wengang,Duan, Hao,Wei, Dezhou,Cui, Baoyu,Wang, Xinyang. "Stability of diethyl dithiocarbamate chelates with Cu(II), Zn(II) and Mn(II)". . p. 375 - 381. Retrieved 2019/03/06.
• 2、 Hasegawa, Yasuchika,Maeda, Masashi,Nakanishi, Takayuki,Doi, Yoshihiro,Hinatsu, Yukio,Fujita, Koji,Tanaka, Katsuhisa,Koizumi, Hitoshi,Fushimi, Koji. "Effective optical faraday rotations of semiconductor EuS nanocrystals with paramagnetic transition-metal ions". . p. 2659 - 2666. Retrieved 2013/03/28.