CID 11253958

Base Information

• Chemical Name: CID 11253958
• CAS No.: 51965-62-9
• Molecular Formula: C16H25NSi
• Molecular Weight: 259.467
• DSSTox Substance ID: DTXSID601143314
• Nikkaji Number: J2.156.740J

Synonyms:DTXSID601143314;51965-62-9;1-(1,1-Dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1-buten-1-ylidene)silanamine

Chemical Property of CID 11253958

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 259.175626336
• Heavy Atom Count: 18
• Complexity: 324

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(=C=N[Si](C)(C)C(C)(C)C)C1=CC=CC=C1

Technology Process of CID 11253958

There total 3 articles about CID 11253958 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2-phenylbutanenitrile (769-68-6) + tert-butyldimethylsilyl chloride (18162-48-6) → 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1-propen-1-ylidene)silanamine (51965-62-9)

Guidance literature:

2-phenylbutanenitrile; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 0.0833333h;

tert-butyldimethylsilyl chloride; In tetrahydrofuran; hexane; at -78 - 20 ℃;

DOI:10.1002/anie.200461886

Reference yield:

phenylacetonitrile (140-29-4) → 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1-propen-1-ylidene)silanamine (51965-62-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 72 percent

2: 1) lithium diisopropylamide / 1) THF, -78 deg C, 60 min; 2) THF, 30 min at -78 deg C, then 60 min at 25 deg C

With lithium diisopropyl amide;

DOI:10.1021/jo00170a043

Reference yield:

→ 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1-propen-1-ylidene)silanamine (51965-62-9)

Guidance literature:

2-Phenylbutyronitril: 1) n-BuLi/i-Pr2NH 2) t-Butyldimethylchlorsilan;

DOI:10.1021/jo00932a028

upstream raw materials:

2-phenylbutanenitrile

tert-butyldimethylsilyl chloride

phenylacetonitrile

Downstream raw materials:

(2R,3S)-3-hydroxy-2-ethyl-3-(2-naphthyl)-2-phenylpropanenitrile

C₂₆H₂₇N₃O

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 51965-62-9 Silanamine, 1-(1,1-dimethylethyl)-1,1-dimethyl-N-(2-phenyl-1-butenylidene)-

Send

Send

Metric Ton KG G Pound L ML

Send

Send