trans-2-Methyl-3-octene

Base Information

• Chemical Name: trans-2-Methyl-3-octene
• CAS No.: 52937-36-7
• Molecular Formula: C9H18
• Molecular Weight: 126.242
• Mol file: 52937-36-7.mol

Synonyms:trans-2-Methyl-3-octene;52937-36-7;2-methyl-3-octene;3-Octene, 2-methyl-;(3E)-2-Methyl-3-octene;(3E)-2-Methyl-3-octene #;RXYSIDRRVRTDIF-BQYQJAHWSA-N;AKOS006274074

Chemical Property of trans-2-Methyl-3-octene

Chemical Property:

• Vapor Pressure: 7.7mmHg at 25°C
• Boiling Point: 140.3°Cat760mmHg
• Flash Point: 27.8°C
• PSA: 0.00000
• Density: 0.737g/cm³
• LogP: 3.38880
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 126.140850574
• Heavy Atom Count: 9
• Complexity: 70.1

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC=CC(C)C
• Isomeric SMILES: CCCC/C=C/C(C)C

Technology Process of trans-2-Methyl-3-octene

There total 9 articles about trans-2-Methyl-3-octene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

isopropyl alcohol (67-63-0,8013-70-5) → 2-Methyl-1-pentene (763-29-1) + (E)-3,7-dimethyloct-2-ene (6874-06-2) + trans-2,6-dimethylhex-3-ene (692-96-6) + (Z)-4-methyl-2-pentene (691-38-3) + (E)-4-methylpent-2-ene (674-76-0) + di-isopropyl ether (108-20-3) + 2,4-dimethyl-2-pentene (625-65-0) + (E)-non-4-ene (10405-85-3,2198-23-4) + (E)-2,3-dimethyl-hept-3-ene (59643-74-2) + trans-2-methyl-3-octene (52937-36-7)

Guidance literature:

With zeolite ZSM-5; at 400 ℃; for 425h; under 15201 Torr; Fixed bed reactor;

DOI:10.1021/ja907692t

Reference yield:

(E)-5-decene (7433-56-9) + (E)-2,5-dimethylhex-3-ene (692-70-6) → trans-2-methyl-3-octene (52937-36-7)

Guidance literature:

dichloro[1,3-bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene) (tricyclohexylphosphine) ruthenium(II); In dichloromethane; at 40 ℃; for 0.5 - 40h; Conversion of starting material;

Reference yield:

2-Triethylsilanyl-hexan-1-ol (152841-71-9) → trans-2-methyl-3-octene (52937-36-7)

Guidance literature:

Multi-step reaction with 2 steps

1: (COCl)2, Et₃N / dimethylsulfoxide; CH₂Cl₂

2: 2.) KH / 1.) THF, -78 deg C, 2.) THF

With oxalyl dichloride; potassium hydride; triethylamine; In dichloromethane; dimethyl sulfoxide;

DOI:10.1016/S0040-4039(00)79203-3

upstream raw materials:

n-butyllithium

trans-1-(tributylstannyl)-1,2-epoxy-3-methylbutane

isopropylmagnesium chloride

(Z)-2-(1-hexenyl)-1,3,2-dioxaborinane