trans-5-Decene

Base Information

• Chemical Name: trans-5-Decene
• CAS No.: 7433-56-9
• Molecular Formula: C10H20
• Molecular Weight: 140.269
• European Community (EC) Number: 231-080-7
• NSC Number: 147121,95430
• UNII: Z8FZ66YW4V
• DSSTox Substance ID: DTXSID30873229
• Nikkaji Number: J40.820D,J82.888B
• Wikidata: Q81978758
• Metabolomics Workbench ID: 5292
• Mol file: 7433-56-9.mol

Synonyms:trans-5-Decene;7433-56-9;(E)-5-Decene;5-DECENE, (E)-;(E)-dec-5-ene;trans-Dec-5-ene;5E-decene;5-decene, (5E)-;EINECS 231-080-7;NSC 95430;BRN 1719487;Z8FZ66YW4V;NSC-95430;4-01-00-00902 (Beilstein Handbook Reference);MFCD00009508;(5E)-5-Decene;5-trans-Decene;.epsilon.-trans-Decene;(5E)-dec-5-ene;trans-5-Decene, 99%;(5E)-5-Decene #;UNII-Z8FZ66YW4V;(5Z)-DEC-5-ENE;DTXSID30873229;NSC95430;LMFA11000597;NSC147121;AKOS040751458;NSC-147121;(E)-5-C10H20;LS-59414

Chemical Property of trans-5-Decene

Chemical Property:

• Appearance/Colour: clear, colorless liquid.
• Vapor Pressure: 2.08mmHg at 25°C
• Melting Point: -73°C
• Refractive Index: n20/D 1.424(lit.)
• Boiling Point: 169 °C at 760 mmHg
• Flash Point: 46.1 °C
• PSA: 0.00000
• Density: 0.749 g/cm³
• LogP: 3.92300
• Water Solubility.: Insoluble in water.
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 140.156500638
• Heavy Atom Count: 10
• Complexity: 62.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

trans-5-Decene 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 16-26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: CCCCC=CCCCC
• Isomeric SMILES: CCCC/C=C/CCCC
• Uses: trans-5-Decene has been used to characterize the effect of cyclization and size on the stability of Criegee intermediates formed in ozonolysis. It has been added to phenoxathiin cation radical in acetonitrile solution to form bis(10-phenoxathiiniumyl) alkane adducts.

Technology Process of trans-5-Decene

There total 92 articles about trans-5-Decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

5-decyne (1942-46-7) → (E)-5-decene (7433-56-9)

Guidance literature:

With silver(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate; C₁₉H₁₃I₂N₃O₂Ru; hydrogen; In water; at 80 ℃; for 2h; under 3750.38 Torr; chemoselective reaction; Autoclave; Schlenk technique;

DOI:10.1021/acs.organomet.0c00413

Reference yield: 91.0%

(Z)-5-(Trimethylsilyl)-5-decene (57266-88-3) → (E)-5-decene (7433-56-9)

Guidance literature:

With hydrogen iodide; In benzene; at 20 ℃; for 2h;

Reference yield: 80.0%

trans-2,3-dibutyloxirane (2165-61-9) → (E)-5-decene (7433-56-9)

Guidance literature:

With n-Bu₃Sn-AlMe₃Li; In tetrahydrofuran; hexane; at 25 ℃; for 18h;

DOI:10.1246/bcsj.58.1480

upstream raw materials:

5-decyne

n-butyl magnesium bromide

(Z)-1-n-Butyl-2-phenylthioethene

(E)-1-n-Butyl-2-phenylthioethene

Downstream raw materials:

erythro-<1-butyl-2-(phenylseleno)hexyl>cyanamide

(5R,6S)-6-Phenylselanyl-decan-5-ol

erythro-t-butyl <1-butyl-2(phenylseleno)hexyl>carbamate

(1-Butyl-2-phenylselanyl-hexyl)-carbamic acid tert-butyl ester

Refernces

• 1、 Bochkarev,Begantsova,Platonova,Basova,Grigor'eva,Stolyarova,Malysheva,Fukin,Baranov,Kurskii,Bochkarev,Abakumov. "Effect of the nature of carbene fragments in the tungsten complexes PhMe2E-CH=W(NAr)(OR')2 and Me3E-CH=W(NAr)(OR') 2 (E = C, Si) on their catalytic properties in olefin metathesis reactions". . p. 1874 - 1879. Retrieved 2008.
• 2、 -. "SYNTHESIS OF PHEROMONE DERIVATIVES VIA Z-SELECTIVE OLEFIN METATHESIS". Paragraph 0222; 0226-0229. . Retrieved 2021/12/28.
• 3、 Buchmeiser, Michael R.,Frey, Wolfgang,Musso, Janis V.,Schowner, Roman. "Cationic Tungsten Imido Alkylidene N-Heterocyclic Carbene Complexes That Contain Bulky Ligands". . p. 3145 - 3157. Retrieved 2021/09/30.