N-Decylbenzamide

Base Information

• Chemical Name: N-Decylbenzamide
• CAS No.: 53044-19-2
• Molecular Formula: C17H27NO
• Molecular Weight: 261.407
• Mol file: 53044-19-2.mol

Synonyms:N-n-Decylbenzamid;

Chemical Property of N-Decylbenzamide

Chemical Property:

• PSA: 29.10000
• LogP: 4.94800

Purity/Quality:

N-DECYL-BENZAMIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-Decylbenzamide

There total 5 articles about N-Decylbenzamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-aminodecane (2016-57-1) + benzoic acid (65-85-0,8013-63-6) → N-decylbenzamide (53044-19-2)

Guidance literature:

With montmorillonite KSF; at 20 - 250 ℃; Microwave irradiation;

DOI:10.2174/1570178611310020011

Reference yield: 81.0%

n-decyl perchlorate + benzonitrile (100-47-0) → N-decylbenzamide (53044-19-2)

Guidance literature:

n-decyl perchlorate; benzonitrile; In neat (no solvent); at 75 ℃; for 3h; Inert atmosphere;

With water;

DOI:10.1007/s11172-020-2858-8

Reference yield: 58.0%

1-aminodecane (2016-57-1) + benzyl alcohol (100-51-6,185532-71-2) → N-decylbenzamide (53044-19-2)

Guidance literature:

With RuCl₂(2-aminomethylpyridine)(dppf); potassium hydroxide; at 125 ℃; for 3.5h; Neat (no solvent);

DOI:10.1021/om2004755

upstream raw materials:

1-aminodecane

2,2,2-trichloroacetophenone

benzyl alcohol

benzoic acid

Downstream raw materials:

2-{3-(benzyl-decyl-amino)-1-[2-(benzyl-decyl-amino)-ethyl]-propyl}-malonic acid diethyl ester

N-benzyl-decan-1-amine

N-benzylidenedecan-1-amine

Refernces

• 1、 Das, Jagadish,Banerjee, Debasis. "Nickel-Catalyzed Phosphine Free Direct N-Alkylation of Amides with Alcohols". . p. 3378 - 3384. Retrieved 2018/03/26.
• 2、 Schley, Nathan D.,Dobereiner, Graham E.,Crabtree, Robert H.. "Oxidative synthesis of amides and pyrroles via dehydrogenative alcohol oxidation by ruthenium diphosphine diamine complexes". scheme or table. p. 4174 - 4179. Retrieved 2011/10/03.