Benzene, 1,1'-(6-fluoro-1-hexenylidene)bis-

Base Information

Chemical Name:Benzene, 1,1'-(6-fluoro-1-hexenylidene)bis-
CAS No.:548459-52-5
Molecular Formula:C18H19F
Molecular Weight:254.347
Hs Code.:
DSSTox Substance ID:DTXSID40460240
Nikkaji Number:J1.909.554A

Synonyms:Benzene, 1,1'-(6-fluoro-1-hexenylidene)bis-;548459-52-5;DTXSID40460240

Suppliers and Price of Benzene, 1,1'-(6-fluoro-1-hexenylidene)bis-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Benzene, 1,1'-(6-fluoro-1-hexenylidene)bis-

Chemical Property:

XLogP3:5.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:6
Exact Mass:254.147078768
Heavy Atom Count:19
Complexity:237

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C(=CCCCCF)C2=CC=CC=C2

Technology Process of Benzene, 1,1'-(6-fluoro-1-hexenylidene)bis-

There total 1 articles about Benzene, 1,1'-(6-fluoro-1-hexenylidene)bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 169138-21-0
6,6-diphenyl-5-hexene-1-ol

: 548459-52-5
1,1-diphenyl-6-fluoro-1-hexene

Guidance literature:: With diethylamino-sulfur trifluoride; In dichloromethane; at 0 ℃; for 18h;
DOI:10.1002/anie.201503288 DOI:10.1002/anie.201601126

Reference yield: 96.0%

: 677-22-5
tert-butylmagnesium chloride

: 548459-52-5
1,1-diphenyl-6-fluoro-1-hexene

: 7,7-dimethyl-1,1-diphenyloct-1-ene

Guidance literature:: With penta-1,3-diene; cobalt(II) chloride; lithium iodide; In tetrahydrofuran; at -78 - 50 ℃; for 24h;
DOI:10.1021/acs.orglett.7b01370

Reference yield: 93.0%

: 106-99-0,130983-70-9,29406-96-0,9003-17-2
buta-1,3-diene

: 21450-64-6
(2,6-dimethylphenyl)magnesium bromide

: 548459-52-5
1,1-diphenyl-6-fluoro-1-hexene

: (E)-12-(2,6-dimethylphenyl)-1,1-diphenyl-7-vinyldodec-1,10-diene

Guidance literature:: With nickel(II) bromide dimethoxyethane; In tetrahydrofuran; at -78 - 40 ℃; for 10h; regioselective reaction; Inert atmosphere;
DOI:10.1002/anie.201601126