Benzeneundecanol, 3-methoxy-

Base Information

• Chemical Name: Benzeneundecanol, 3-methoxy-
• CAS No.: 557786-44-4
• Molecular Formula: C18H30O2
• Molecular Weight: 278.435
• Mol file: 557786-44-4.mol

Synonyms:

Chemical Property of Benzeneundecanol, 3-methoxy-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzeneundecanol, 3-methoxy-

There total 2 articles about Benzeneundecanol, 3-methoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

undec-10-yn-1-ol (2774-84-7) → 11-(3-methoxyphenyl)undecan-1-ol (557786-44-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 93 percent / Et₃N; PPh₃; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ / CuI / 24 h / 70 °C

2: 96 percent / H₂ / 10 percent Pd/C / ethanol / 12 h / 20 °C / atmospheric pressure

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; hydrogen; triethylamine; triphenylphosphine; palladium on activated charcoal; copper(l) iodide; In ethanol;

DOI:10.1021/ja0300463

Reference yield:

3-methoxy-1-iodobenzene (766-85-8) → 11-(3-methoxyphenyl)undecan-1-ol (557786-44-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 93 percent / Et₃N; PPh₃; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ / CuI / 24 h / 70 °C

2: 96 percent / H₂ / 10 percent Pd/C / ethanol / 12 h / 20 °C / atmospheric pressure

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; hydrogen; triethylamine; triphenylphosphine; palladium on activated charcoal; copper(l) iodide; In ethanol;

DOI:10.1021/ja0300463

Reference yield: 90.0%

11-(3-methoxyphenyl)undecan-1-ol (557786-44-4) → 1-bromo-11-(3-methoxyphenyl)undecane (557786-45-5)

Guidance literature:

With carbon tetrabromide; triphenylphosphine; In dichloromethane; at 0 - 20 ℃; for 7h;

DOI:10.1021/ja0300463

upstream raw materials:

undec-10-yn-1-ol

3-methoxy-1-iodobenzene

Downstream raw materials:

1-bromo-11-(3-methoxyphenyl)undecane

[11-(3-methoxyphenyl)undecyl]methylamine

[11-(3-methoxyphenyl)undecyl]methylcarbamic acid tert-butyl ester