6-Hepten-3-ol, 4-(phenylmethoxy)-, (3S,4R)-

Base Information

Chemical Name:6-Hepten-3-ol, 4-(phenylmethoxy)-, (3S,4R)-
CAS No.:558459-28-2
Molecular Formula:C14H20O2
Molecular Weight:220.312
Hs Code.:

Synonyms:

Suppliers and Price of 6-Hepten-3-ol, 4-(phenylmethoxy)-, (3S,4R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 6-Hepten-3-ol, 4-(phenylmethoxy)-, (3S,4R)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 6-Hepten-3-ol, 4-(phenylmethoxy)-, (3S,4R)-

There total 6 articles about 6-Hepten-3-ol, 4-(phenylmethoxy)-, (3S,4R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 924-41-4
1,5-hexadiene-3-ol

: 558459-28-2
(3S,4R)-4-benzyloxy-hept-6-en-3-ol

Guidance literature:: Multi-step reaction with 3 steps

1.1: (-)-dicyclohexyl tartrate; Ti(OiPr)4; 4 Angstroem molecular sieves / CH₂Cl₂ / 0.5 h / -20 °C

1.2: 42 percent / t-BuOOH / CH₂Cl₂ / 19 h / -20 °C

2.1: 87 percent / Bu₄NI; NaH / tetrahydrofuran / -78 - 25 °C

3.1: 90 percent / CuI / tetrahydrofuran; diethyl ether / 1 h / -20 °C

With titanium(IV) isopropylate; copper(l) iodide; (-)-dicyclohexyl D-tartrate; 4 A molecular sieve; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/ja029956v

Reference yield:

: 558459-27-1
(1R)-1-[(1S)-oxiranyl]-but-3-en-1-ol

: 558459-28-2
(3S,4R)-4-benzyloxy-hept-6-en-3-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / Bu₄NI; NaH / tetrahydrofuran / -78 - 25 °C

2: 90 percent / CuI / tetrahydrofuran; diethyl ether / 1 h / -20 °C

With copper(l) iodide; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; diethyl ether;
DOI:10.1021/ja029956v

Reference yield:

: 236110-81-9
(4S)-4-benzyl-3-[2-(benzyloxy)acetyl]-1,3-oxazolan-2-one

: 558459-28-2
(3S,4R)-4-benzyloxy-hept-6-en-3-ol

Guidance literature:: Multi-step reaction with 4 steps

1: 75 percent / sodium bis(trimethylsilyl)amide / toluene; tetrahydrofuran / 3.5 h / -45 °C

2: 89 percent / lithium borohydride / methanol; diethyl ether; tetrahydrofuran / 1.5 h

3: oxalyl chloride; dimethyl sulfoxide; triethylamine / CH₂Cl₂ / 20 °C

4: zinc bromide / diethyl ether / 1 h

With lithium borohydride; oxalyl dichloride; sodium hexamethyldisilazane; dimethyl sulfoxide; triethylamine; zinc dibromide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; toluene; 3: Swern oxidation;
DOI:10.1021/ol991201e