Tetradecyl phosphinic acid

Base Information

• Chemical Name: Tetradecyl phosphinic acid
• CAS No.: 2753-41-5
• Molecular Formula: C14H31 O2 P
• Molecular Weight: 261.36
• DSSTox Substance ID: DTXSID20950210
• Wikidata: Q82928209
• Mol file: 2753-41-5.mol

Synonyms:Tetradecyl phosphinic acid;Phosphinic acid, tetradecyl-;2753-41-5;C14H31O2P;C14-H31-O2-P;SCHEMBL4481764;DTXSID20950210;LS-106211;[Oxo(tetradecyl)-lambda~5~-phosphanylidene]oxidanium

Chemical Property of Tetradecyl phosphinic acid

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 60.77000
• Density: g/cm³
• LogP: 5.15450
• XLogP3: 5.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 13
• Exact Mass: 261.19834219
• Heavy Atom Count: 17
• Complexity: 172

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCCC[P+](=O)O

Technology Process of Tetradecyl phosphinic acid

There total 5 articles about Tetradecyl phosphinic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

1-tetradecene (1120-36-1) → tetradecyl-H-phosphinic acid (2753-41-5)

Guidance literature:

With sodium hypophosphite monohydrate; 2,2'-azobis(isobutyronitrile); sulfuric acid; In ethanol; for 24h; Reflux;

DOI:10.1039/c2ob26395e

Reference yield: 69.0%

1-Bromotetradecane (112-71-0) → tetradecyl-H-phosphinic acid (2753-41-5)

Guidance literature:

With potassium hydroxide semihydrate; phosphorus; In water; toluene; at 85 - 90 ℃; for 6h; chemoselective reaction; Inert atmosphere;

DOI:10.1039/d1ob01470f

Reference yield:

C16H35O2P → tetradecyl-H-phosphinic acid (2753-41-5)

Guidance literature:

With sodium hydroxide; In water; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/acs.jmedchem.0c01294

upstream raw materials:

1-tetradecene

n-tetradecylmagnesium chloride

C₁₈H₃₉O₂P

1-Bromotetradecane