1-Tetradecene

Base Information

• Chemical Name: 1-Tetradecene
• CAS No.: 1120-36-1
• Deprecated CAS: 2136578-31-7
• Molecular Formula: C14H28
• Molecular Weight: 196.376
• Hs Code.: 29012990
• European Community (EC) Number: 214-306-9
• ICSC Number: 1566
• NSC Number: 66434
• UNII: FW23481S7S
• DSSTox Substance ID: DTXSID4027367
• Nikkaji Number: J44.092B
• Wikidata: Q27147080
• RXCUI: 1314225
• Metabolomics Workbench ID: 5027
• ChEMBL ID: CHEMBL1892257
• Mol file: 1120-36-1.mol

Synonyms:1-TETRADECENE;1120-36-1;Tetradec-1-ene;Tetradecene;n-Tetradec-1-ene;1-Tetradecylene;alpha-Tetradecene;1-butadecene;Neodene 14;CCRIS 3785;HSDB 1087;AI3-10509;EINECS 214-306-9;NSC 66434;.alpha.-Tetradecene;UNII-FW23481S7S;DTXSID4027367;CHEBI:77505;FW23481S7S;NSC-66434;DTXCID907367;Alkenes, C10-16 .alpha.-;EC 214-306-9;MFCD00008981;1-Tetradecene [Standard Material for GC];68855-58-3;dodecylethylene;a-Tetradecene;aplha-Tetradecene;Tetradecene-1;NSC66434;TETRADECENE [INCI];Alkenes, C14-18 alpha-;Alkenes, C14-20 alpha-;1-TETRADECENE [HSDB];CHEMBL1892257;1-Tetradecene, analytical standard;BAA12036;EINECS 272-493-2;EINECS 272-494-8;Tox21_303051;LMFA11000329;1-Tetradecene, >=97.0% (GC);1-Tetradecene, technical grade, 92%;AKOS015904124;NCGC00164372-01;NCGC00257042-01;CAS-1120-36-1;LS-163757;CS-0314332;FT-0608312;T0087;J-002695;Q27147080

Chemical Property of 1-Tetradecene

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 1.65Pa at 25℃
• Melting Point: -13--11 °C(lit.)
• Refractive Index: n20/D 1.436(lit.)
• Boiling Point: 251.574 °C at 760 mmHg
• Flash Point: 115.556 °C
• PSA: 0.00000
• Density: 0.771 g/cm³
• LogP: 5.48340
• Storage Temp.: Store below +30°C.
• Water Solubility.: Soluble in hydrocarbon solvents; insoluble in water.
• XLogP3: 7.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 11
• Exact Mass: 196.219100893
• Heavy Atom Count: 14
• Complexity: 105

Purity/Quality:

99.9% ^*data from raw suppliers

1-Tetradecene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,Xn
• Statements: 36/37-66-65
• Safety Statements: 26-36-62

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: CCCCCCCCCCCCC=C
• Inhalation Risk: A harmful contamination of the air will not or will only very slowly be reached on evaporation of this substance at 20 °C; on spraying or dispersing, however, much faster.
• Effects of Short Term Exposure: If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis.
• Effects of Long Term Exposure: The substance defats the skin, which may cause dryness or cracking.
• Uses: Solvent in perfumes, flavors, medicines, dyes, oils, resins. 1-Tetradecene is a useful organic building block

Technology Process of 1-Tetradecene

There total 87 articles about 1-Tetradecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

pentadecanol (629-76-5) → 1-tetradecene (1120-36-1) + tetradecane (629-59-4)

Guidance literature:

With benzophenone; potassium carbonate; rhodium(III) chloride; bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; 1,3-bis-(diphenylphosphino)propane; at 170 ℃; Heating;

DOI:10.1002/adsc.200600228

Reference yield: 16.0%

1-Tetradecene sulfide (26072-89-9) → 1-tetradecene (1120-36-1) + tetradecane (629-59-4) + trans-2-tetradecene (35953-54-9)

Guidance literature:

With nickel; In ethanol; at 90 ℃; for 0.5h;

DOI:10.1016/S0040-4039(00)81737-2

Reference yield: 11.0%

1-iodotetradecane (19218-94-1) → 1-tetradecene (1120-36-1) + tetradecane (629-59-4) + octacosane (630-02-4) + 1-tetradecanol methyl ether (7388-90-1)

Guidance literature:

With sodium hydroxide; palladium dichloride; In methanol; for 6h; Product distribution; Heating; var. reducing agents, other organic halides;

DOI:10.1246/bcsj.54.3599

upstream raw materials:

1-Tetradecanol

myristyl palmitate

undecylmagnesium bromide

allyl bromide

Downstream raw materials:

tetradec-2-enyl-succinic acid

1,2-epoxytetradecane

tetradecyl-phosphonic acid dimethyl ester

tetradecane-1,2-diol

Refernces

• 1、 Curran,Van Elburg. "Approximate rate constants for the addition of alkyl radicals to allylstannanes". . p. 2861 - 2864. Retrieved 1990.
• 2、 Feldhues, Michael,Schafer, Hans. J.. "SELECTIVE MIXED COUPLING OF CARBOXYLIC ACIDS-III. SYNTHESIS OF CYCLOPENTADECANONE FROM CYCLIC TETRAACYL DIPEROXIDES". . p. 1285 - 1290. Retrieved 1986.
• 3、 Posner et al.. "". . p. 281. Retrieved 1972.
• 4、 Zhou, Wen,Napoline, Jonathan Wesley,Thomas, Christine M.. "A catalytic application of Co/Zr heterobimetallic complexes: Kumada coupling of unactivated alkyl halides with alkyl grignard reagents". . p. 2029 - 2033. Retrieved 2011.
• 5、 Maetani, Shinji,Fukuyama, Takahide,Suzuki, Nobuyoshi,Ishihara, Daisuke,Ryu, Ilhyong. "Efficient iridium-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to internal or terminal alkenes". . p. 1389 - 1394. Retrieved 2011.
• 6、 Bloomer, Brandon,Butcher, Trevor W.,Ciccia, Nicodemo R.,Conk, Richard J.,Hanna, Steven,Hartwig, John F.. "Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydroboration and Dehydroboration". supporting information. p. 1005 - 1010. Retrieved 2022/02/10.
• 7、 Chen, Qiang,Suo, Hongyi,Zhang, Wenjuan,Zhang, Randi,Solan, Gregory A.,Liang, Tongling,Sun, Wen-Hua. "1,5-Naphthyl-linked bis(imino)pyridines as binucleating scaffolds for dicobalt ethylene oligo-/polymerization catalysts: Exploring temperature and steric effects". supporting information. p. 8264 - 8278. Retrieved 2019/06/18.