3,3-Dimethyl-2-methylidenebicyclo[2.2.1]heptane-1-carboxamide

Base Information

Chemical Name:3,3-Dimethyl-2-methylidenebicyclo[2.2.1]heptane-1-carboxamide
CAS No.:56022-40-3
Molecular Formula:C₁₁H₁₇NO
Molecular Weight:179.262
Hs Code.:
DSSTox Substance ID:DTXSID40377869

Synonyms:56022-40-3;3,3-dimethyl-2-methylidenebicyclo[2.2.1]heptane-1-carboxamide;Bicyclo[2.2.1]heptane-1-carboxamide, 3,3-dimethyl-2-methylene-;AC1MCIIX;IFLab1_004013;DTXSID40377869;HMS1423G09;STL227699;AKOS000267905;AKOS016038834;SR-01000446435;SR-01000446435-1

Suppliers and Price of 3,3-Dimethyl-2-methylidenebicyclo[2.2.1]heptane-1-carboxamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 3,3-Dimethyl-2-methylidenebicyclo[2.2.1]heptane-1-carboxamide

Chemical Property:

XLogP3:1.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:179.131014166
Heavy Atom Count:13
Complexity:293

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2CCC(C2)(C1=C)C(=O)N)C

Technology Process of 3,3-Dimethyl-2-methylidenebicyclo[2.2.1]heptane-1-carboxamide

There total 1 articles about 3,3-Dimethyl-2-methylidenebicyclo[2.2.1]heptane-1-carboxamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.5%

: 151-50-8
potassium cyanide

: 3-benzoyloxyiminocamphornitrimine

: 93-58-3,5705-52-2,80226-58-0
benzoic acid methyl ester

: 51468-52-1,56022-40-3,63187-34-8
camphene-1-carboxamide

Guidance literature:: In methanol; Ambient temperature;

Reference yield:

: 51468-52-1,56022-40-3,63187-34-8
camphene-1-carboxamide

: (1R,4S)-1-(1,1-Dimethyl-3,3-diphenyl-allyl)-3,3-dimethyl-2-methylene-bicyclo[2.2.1]heptane

Guidance literature:: Multi-step reaction with 7 steps

1: aq. KOH / ethanol

2: diethyl ether

3: NH₄OAc, AcOH / benzene

4: (i) MeLi, CuI, Et₂O, (ii) KOH, HOCH₂CH₂OH

6: diethyl ether

7: Al₂O₃ / 230 - 235 °C

With aluminum oxide; potassium hydroxide; ammonium acetate; acetic acid; In diethyl ether; ethanol; benzene;
DOI:10.1016/S0040-4020(01)97858-5

Reference yield:

: 51468-52-1,56022-40-3,63187-34-8
camphene-1-carboxamide

: 3-((1S,4R)-3,3-Dimethyl-2-methylene-bicyclo[2.2.1]hept-1-yl)-3-methyl-1,1-diphenyl-butan-1-ol

Guidance literature:: Multi-step reaction with 6 steps

1: aq. KOH / ethanol

2: diethyl ether

3: NH₄OAc, AcOH / benzene

4: (i) MeLi, CuI, Et₂O, (ii) KOH, HOCH₂CH₂OH

6: diethyl ether

With potassium hydroxide; ammonium acetate; acetic acid; In diethyl ether; ethanol; benzene;
DOI:10.1016/S0040-4020(01)97858-5