1,2-Epoxy-3-(propenyloxy)propane

Base Information

• Chemical Name: 1,2-Epoxy-3-(propenyloxy)propane
• CAS No.: 1607-23-4
• Molecular Formula: C6H10 O2
• Molecular Weight: 114.144
• Hs Code.: 2910900090
• European Community (EC) Number: 216-530-2
• Nikkaji Number: J195.227G
• Mol file: 1607-23-4.mol

Synonyms:1,2-Epoxy-3-(propenyloxy)propane;1607-23-4;2-[[(E)-prop-1-enoxy]methyl]oxirane;EINECS 216-530-2;SCHEMBL2725302;SCHEMBL4435149;1-Propenyl(oxiranylmethyl) ether;Oxirane, [(1-propenyloxy)methyl]-

Chemical Property of 1,2-Epoxy-3-(propenyloxy)propane

Chemical Property:

• Vapor Pressure: 6.82mmHg at 25°C
• Boiling Point: 143.1°Cat760mmHg
• Flash Point: 39.6°C
• PSA: 21.76000
• Density: 0.993g/cm³
• LogP: 0.93540
• XLogP3: 0.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 114.068079557
• Heavy Atom Count: 8
• Complexity: 88.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=COCC1CO1
• Isomeric SMILES: C/C=C/OCC1CO1

Technology Process of 1,2-Epoxy-3-(propenyloxy)propane

There total 6 articles about 1,2-Epoxy-3-(propenyloxy)propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.9%

Allyl glycidyl ether (106-92-3,25639-25-2,90907-93-0) + Triethoxysilane (998-30-1) → triethoxy(2-glycidoxy-1-methylethyl)silane + glycidyl 1-propenyl ether (1607-23-4) + tetraethoxy orthosilicate (78-10-4) + (3-glycidyloxypropyl)triethoxysilane (2602-34-8)

Guidance literature:

Speier's catalyst; at 70 - 90 ℃; for 1.5h; Further byproducts.;

DOI:10.1134/S1070363207010082

Reference yield: 70.7%

Allyl glycidyl ether (106-92-3,25639-25-2,90907-93-0) + 1,1,3,3-Tetramethyldisiloxane (3277-26-7) → glycidyl 1-propenyl ether (1607-23-4) + 1,3-bis(glycidyloxypropyl)-1,1,3,3-tetramethyldisiloxane (126-80-7) + 1,1,3,3-tetramethyl-1-(3-(oxiran-2-ylmethoxy)propyl)disiloxane (17980-29-9) + 1-(1-methyl-2-glycidoxyethyl)-1,1,3,3-tetramethyldisiloxane (1567764-85-5)

Guidance literature:

With [{SiO₂}O₂Si(Me)(CH₂)3SBu]2PtCl₂; In toluene; at 80 ℃; for 10h; regioselective reaction;

DOI:10.1134/S107036321801005X

Reference yield:

Allyl glycidyl ether (106-92-3,25639-25-2,90907-93-0) → glycidyl 1-propenyl ether (1607-23-4)

Guidance literature:

With 1,1,3,3-Tetramethyldisiloxane; In toluene; at 80 ℃; for 7h; Temperature; Time;

DOI:10.1134/S1070363220010107

upstream raw materials:

Allyl glycidyl ether

Triethoxysilane

1,1,3,3-Tetramethyldisiloxane