Dispiro[1,2,4-dioxazolidine-3,1':5,1''-dicyclohexane]

Base Information

• Chemical Name: Dispiro[1,2,4-dioxazolidine-3,1':5,1''-dicyclohexane]
• CAS No.: 21842-28-4
• Molecular Formula: C12H21NO2
• Molecular Weight: 211.304
• Mol file: 21842-28-4.mol

Synonyms:1,1'-peroxy-dicyclohexyl amine;

Chemical Property of Dispiro[1,2,4-dioxazolidine-3,1':5,1''-dicyclohexane]

Chemical Property:

• Melting Point: 40.0-41.5 °C
• Boiling Point: 138-140 °C(Press: 12 Torr)
• PKA: 5.97±0.20(Predicted)
• PSA: 30.49000
• Density: 1.10±0.1 g/cm3(Predicted)
• LogP: 3.18740

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Dispiro[1,2,4-dioxazolidine-3,1':5,1''-dicyclohexane]

There total 2 articles about Dispiro[1,2,4-dioxazolidine-3,1':5,1''-dicyclohexane] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.9%

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → 14,15-dioxa-7-aza-dispiro[5.1.5.2]pentadecane (21842-28-4)

Guidance literature:

With ammonium hydroxide; dihydrogen peroxide; sodium carbonate; at 100 ℃; for 0.166667h; Temperature; Reagent/catalyst;

Reference yield:

→ 14,15-dioxa-7-aza-dispiro[5.1.5.2]pentadecane (21842-28-4)

Guidance literature:

1,1'-Dihydroxydicyclohexylperoxid, aq.konz.NH4OH, EDTA;

Reference yield: 99.2%

14,15-dioxa-7-aza-dispiro[5.1.5.2]pentadecane (21842-28-4) → caprolactam (105-60-2,9012-16-2) + 11-cyanoundecanoic acid (5810-18-4) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4)

Guidance literature:

With cerium(IV) oxide; 2,2'-azobis(isobutyronitrile); at 50 ℃; for 12h; Reagent/catalyst; Temperature; Inert atmosphere;

upstream raw materials:

cyclohexanone

Downstream raw materials:

11-cyanoundecanoic acid

1,10-decanedicarboxamide

caprolactam

cyclohexanone

Refernces