p-Methoxybenzyl trichloroacetate

Base Information

• Chemical Name: p-Methoxybenzyl trichloroacetate
• CAS No.: 56599-24-7
• Molecular Formula: C10H9Cl3O3
• Molecular Weight: 283.539
• DSSTox Substance ID: DTXSID40543502
• Nikkaji Number: J1.591.944B
• Wikidata: Q82420406
• Mol file: 56599-24-7.mol

Synonyms:p-methoxybenzyl trichloroacetate;56599-24-7;p-methoxy-benzyltrichloroacetate;SCHEMBL10551219;DTXSID40543502;VFIXVKDRDKINBP-UHFFFAOYSA-N;(4-Methoxyphenyl)methyl trichloroacetate

Chemical Property of p-Methoxybenzyl trichloroacetate

Chemical Property:

• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 281.961727
• Heavy Atom Count: 16
• Complexity: 232

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)COC(=O)C(Cl)(Cl)Cl

Technology Process of p-Methoxybenzyl trichloroacetate

There total 1 articles about p-Methoxybenzyl trichloroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ p-methoxybenzyl trichloroacetate (56599-24-7)

Guidance literature:

Anisalkohol, N,N-Dimethylanilin, Trichloracetylchlorid;

DOI:10.1021/jo00912a005

Reference yield: 94.0%

p-methoxybenzyl trichloroacetate (56599-24-7) → 4-Methoxybenzyl alcohol (105-13-5)

Guidance literature:

With indium; water; ammonium chloride; In methanol; for 1h; Heating;

DOI:10.1016/S0040-4039(01)01489-7

Reference yield: 87.0%

p-methoxybenzyl trichloroacetate (56599-24-7) + (3S,4R)-1-[(tert-butyldimethylsilyl)oxy]-4-methylhex-5-en-3-ol (168777-81-9) → tert-Butyl-[(3S,4R)-3-(4-methoxy-benzyloxy)-4-methyl-hex-5-enyloxy]-dimethyl-silane (148933-64-6)

Guidance literature:

With scandium tris(trifluoromethanesulfonate); In tetrahydrofuran;

DOI:10.1016/j.bmcl.2007.02.031

Downstream raw materials:

(E)-(4S,6R,7S)-9-Iodo-4-(4-methoxy-benzyloxy)-7-methyl-6-triisopropylsilanyloxy-non-8-en-2-one

4-Methoxybenzyl alcohol

methyl (2S)-[(4-methoxybenzyl)oxy]-2-methylpropanoate

(4R,5Z,7S)-4-(4-methoxybenzyloxy)-5-methyl-7-(tri-iso-propylsilyloxymethyl)non-5-en-2-one