Furan, 2-(2-nitro-1-propenyl)-

Base Information

• Chemical Name: Furan, 2-(2-nitro-1-propenyl)-
• CAS No.: 33322-20-2
• Molecular Formula: C7H7 N O3
• Molecular Weight: 153.137
• Hs Code.: 2932190090
• NSC Number: 35560
• Nikkaji Number: J1.014.927D
• Wikidata: Q76325852
• Mol file: 33322-20-2.mol

Synonyms:2-(2-nitro-1-propenyl)furan;UC 244;UC-244

Chemical Property of Furan, 2-(2-nitro-1-propenyl)-

Chemical Property:

• Vapor Pressure: 0.105mmHg at 25°C
• Boiling Point: 229.5°Cat760mmHg
• Flash Point: 92.6°C
• PSA: 58.96000
• Density: 1.217g/cm³
• LogP: 2.44030
• XLogP3: 2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 153.042593085
• Heavy Atom Count: 11
• Complexity: 183

Purity/Quality:

97% ^*data from raw suppliers

2-(2-Nitroprop-1-en-1-yl)furan 95%+ ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CC1=CC=CO1)[N+](=O)[O-]
• Isomeric SMILES: C/C(=C/C1=CC=CO1)/[N+](=O)[O-]

Technology Process of Furan, 2-(2-nitro-1-propenyl)-

There total 2 articles about Furan, 2-(2-nitro-1-propenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

furfural (98-01-1) + Nitroethane (79-24-3) → 2-(2-methyl-2-nitrovinyl)-furan (33322-20-2)

Guidance literature:

With (2-hydroxyethyl)ammonium formate; at 20 ℃; for 1.2h; Ionic liquid;

DOI:10.1021/jo101696z

Reference yield: 69.0%

Nitroethane (79-24-3) + furan-2-ylmethanamine (617-89-0) → 2-(2-methyl-2-nitrovinyl)-furan (33322-20-2)

Guidance literature:

With 4-(4-fluorophenyl)naphthalene-1,2-dione; oxygen; at 80 ℃; for 12h;

DOI:10.1021/acscatal.9b03442

Reference yield: 98.0%

2-(2-methyl-2-nitrovinyl)-furan (33322-20-2) + 4-methyl-N-(2-((E)-3-oxo-3-phenylprop-1-en-1-yl)phenyl)benzenesulfonamide (1195694-52-0) → 2-[(2R,3S,4R)-2-(2-furyl)-1,2,3,4-tetrahydro-3-methyl-3-nitro-1-tosyl-4-quinolinyl]-1-phenylethanone

Guidance literature:

2-(2-methyl-2-nitrovinyl)-furan; With 3-((3,5-bis(trifluoromethyl)phenyl)amino)-4-(((S)-(6-methoxyquinoline-4-yl))((1S,2S,4S,5R-5-vinylquinuclidine-2-yl)methyl)amino)cyclobutan-3-ene-1,2-dione; In 1,2-dichloro-ethane; toluene; at 20 ℃; for 0.166667h;

4-methyl-N-(2-((E)-3-oxo-3-phenylprop-1-en-1-yl)phenyl)benzenesulfonamide; In 1,2-dichloro-ethane; toluene; at 20 ℃; for 24h; enantioselective reaction;

DOI:10.1002/adsc.201300670

upstream raw materials:

furfural

Nitroethane

furan-2-ylmethanamine

Downstream raw materials:

C₁₈H₁₇NO₃

4-(furan-2-yl)-5-methyl-3-(phenylsulfonyl)-1H-pyrazole

C₁₈H₁₇NO₃

4-furan-2-yl-5-methyl-2-phenyl-1H-imidazole