1-(Allyloxy)-2-bromobenzene

Base Information

• Chemical Name: 1-(Allyloxy)-2-bromobenzene
• CAS No.: 25244-30-8
• Molecular Formula: C9H9 Br O
• Molecular Weight: 213.074
• Hs Code.: 2909309090
• Nikkaji Number: J362.364E
• Mol file: 25244-30-8.mol

Synonyms:60333-75-7;1-(allyloxy)-2-bromobenzene;1-bromo-2-prop-2-enoxybenzene;1-BroMo-2-(2-propen-1-yloxy)-benzene;1-allyloxy-2-bromobenzene;1-BROMO-2-(PROP-2-EN-1-YLOXY)BENZENE;allyl o-bromophenyl ether;benzene, 1-bromo-2-(2-propenyloxy)-;allyl (2-bromophenyl) ether;o-allyloxy-bromo-benzene;o-bromophenyl allyl ether;1-allyloxy-2-bromo-benzene;SCHEMBL930326;PXOIJEJWBLMJHW-UHFFFAOYSA-N;NSC 86570;(2-bromophenyl) (2-propenyl) ether;AKOS000173539;EN300-180559;InChI=1/C9H9BrO/c1-2-7-11-9-6-4-3-5-8(9)10/h2-6H,1,7H

Chemical Property of 1-(Allyloxy)-2-bromobenzene

Chemical Property:

• Vapor Pressure: 0.0286mmHg at 25°C
• Boiling Point: 247.9°Cat760mmHg
• Flash Point: 109.5°C
• PSA: 9.23000
• Density: 1.35g/cm³
• LogP: 3.01390
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 211.98368
• Heavy Atom Count: 11
• Complexity: 125

Purity/Quality:

97% ^*data from raw suppliers

1-Allyloxy-4-bromobenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCOC1=CC=CC=C1Br

Technology Process of 1-(Allyloxy)-2-bromobenzene

There total 16 articles about 1-(Allyloxy)-2-bromobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-bromo-phenol (106-41-2) + allyl bromide (106-95-6) → 4-(allyloxy)bromobenzene (25244-30-8)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 16h;

DOI:10.1016/S0040-4039(99)01835-3

Reference yield: 97.0%

4-bromo-phenol (106-41-2) → 4-(allyloxy)bromobenzene (25244-30-8)

Guidance literature:

With potassium carbonate; In acetone;

DOI:10.1039/b101837j

Reference yield: 95.0%

4-bromophenyl acetate (1927-95-3) + allyl bromide (106-95-6) → 4-(allyloxy)bromobenzene (25244-30-8)

Guidance literature:

With sodium methylate; In N,N-dimethyl-formamide; for 0.5h; Ambient temperature;

DOI:10.1055/s-1997-3267

upstream raw materials:

4-bromo-phenol

allyl bromide

sodium 4-bromophenoxide

3-chloroprop-1-ene

Downstream raw materials:

2-allyl-4-bromophenol

(4-bromo-phenyl)-(2,3-dibromo-propyl)-ether

8-(4'-allyloxyphenyl)-8-hydroxy-1-oxaspiro<4.5>deca-6,9-diene-2-one

2-(4-(allyloxy)phenyl)ethanol