[(4Z)-3-acetyloxy-4-hydroxyimino-6-phenyloxan-2-yl]methyl acetate

Base Information

Chemical Name:[(4Z)-3-acetyloxy-4-hydroxyimino-6-phenyloxan-2-yl]methyl acetate
CAS No.:78465-58-4
Molecular Formula:C16H19NO6
Molecular Weight:321.3252
Hs Code.:
NSC Number:355939
DSSTox Substance ID:DTXSID00423053

Synonyms:NSC355939;78465-58-4;DTXSID00423053;NSC-355939

Suppliers and Price of [(4Z)-3-acetyloxy-4-hydroxyimino-6-phenyloxan-2-yl]methyl acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of [(4Z)-3-acetyloxy-4-hydroxyimino-6-phenyloxan-2-yl]methyl acetate

Chemical Property:

Vapor Pressure:6.31E-10mmHg at 25°C
Boiling Point:477.5°Cat760mmHg
Flash Point:242.6°C
Density:1.29g/cm³
XLogP3:1.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:6
Exact Mass:321.12123733
Heavy Atom Count:23
Complexity:458

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OCC1C(C(=NO)CC(O1)C2=CC=CC=C2)OC(=O)C
Isomeric SMILES:CC(=O)OCC1C(/C(=N\O)/CC(O1)C2=CC=CC=C2)OC(=O)C

Technology Process of [(4Z)-3-acetyloxy-4-hydroxyimino-6-phenyloxan-2-yl]methyl acetate

There total 3 articles about [(4Z)-3-acetyloxy-4-hydroxyimino-6-phenyloxan-2-yl]methyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 78465-54-0
(3,4,6-tri-O-acetyl-2-deoxy-α-D-threo-hex-2-enopyranosyl)benzene

: 78465-58-4
Acetic acid (2R,3R,6S)-2-acetoxymethyl-4-[(E)-hydroxyimino]-6-phenyl-tetrahydro-pyran-3-yl ester

Guidance literature:: With hydroxylamine hydrochloride; In pyridine; at 20 ℃;
DOI:10.1016/0040-4039(81)80119-0

Reference yield:

: 2873-29-2,3685-88-9,4098-06-0,6586-65-8,52485-06-0,63640-41-5,86257-90-1,86257-91-2,87335-77-1,87335-78-2,130931-60-1
3,4,6-triacetyl-D-galactal

: 78465-58-4
Acetic acid (2R,3R,6S)-2-acetoxymethyl-4-[(E)-hydroxyimino]-6-phenyl-tetrahydro-pyran-3-yl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 52 percent / acetic acid / palladium acetate / 80 °C

2: 86 percent / hydroxylamine hydrochloride / pyridine / 20 °C

With hydroxylamine hydrochloride; acetic acid; palladium diacetate; In pyridine;
DOI:10.1016/0040-4039(81)80119-0

Reference yield:

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: 78465-58-4
Acetic acid (2R,3R,6S)-2-acetoxymethyl-4-[(E)-hydroxyimino]-6-phenyl-tetrahydro-pyran-3-yl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 52 percent / acetic acid / palladium acetate / 80 °C

2: 86 percent / hydroxylamine hydrochloride / pyridine / 20 °C

With hydroxylamine hydrochloride; acetic acid; palladium diacetate; In pyridine;
DOI:10.1016/0040-4039(81)80119-0