p-Phenylstyrene oxide

Base Information

• Chemical Name: p-Phenylstyrene oxide
• CAS No.: 36099-26-0
• Molecular Formula: C14H12 O
• Molecular Weight: 196.249
• Hs Code.: 2910900090
• DSSTox Substance ID: DTXSID20957502
• Nikkaji Number: J3.811C
• Mol file: 36099-26-0.mol

Synonyms:p-Phenylstyrene oxide;2-(4-phenylphenyl)oxirane;36099-26-0;4-Phenylstyrene-7,8-oxide;BRN 1425251;Oxirane, (1,1'-biphenyl)-4-yl-;2-{[1,1'-BIPHENYL]-4-YL}OXIRANE;5-17-02-00262 (Beilstein Handbook Reference);Oxirane, [1,1'-biphenyl]-4-yl-;2-([1,1'-Biphenyl]-4-yl)oxirane;p-Phenylstylene oxide;SCHEMBL675866;DTXSID20957502;AKOS000149743;LS-100985;CS-0236155;EN300-1693953;A1-04979;Z278165206

Chemical Property of p-Phenylstyrene oxide

Chemical Property:

• Vapor Pressure: 0.000279mmHg at 25°C
• Boiling Point: 332.6°Cat760mmHg
• Flash Point: 149.7°C
• PSA: 12.53000
• Density: 1.129g/cm³
• LogP: 3.42490
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 196.088815002
• Heavy Atom Count: 15
• Complexity: 199

Purity/Quality:

99% ^*data from raw suppliers

2-(4-Phenylphenyl)oxirane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C(O1)C2=CC=C(C=C2)C3=CC=CC=C3

Technology Process of p-Phenylstyrene oxide

There total 16 articles about p-Phenylstyrene oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

4-Phenylbenzaldehyde (3218-36-8) + diphenyl<(trimethylsilyl)methyl>sulfonium triflate → 2-([1,1′-biphenyl]-4-yl)oxirane (36099-26-0)

Guidance literature:

With cesium fluoride; In dimethyl sulfoxide; for 15h; Ambient temperature;

DOI:10.1055/s-1995-3970

Reference yield: 92.0%

(R)-1-[(1,1'-biphenyl)-4-yl]-2-chloroethan-1-ol → (R)-2-[(1,1'-biphenyl)-4-yl]oxirane (36099-26-0)

Guidance literature:

With potassium carbonate; In methanol; at 10 ℃; for 12h; Inert atmosphere;

DOI:10.1002/adsc.201701227

Reference yield: 87.0%

p-vinylbiphenyl (2350-89-2) → 2-([1,1′-biphenyl]-4-yl)oxirane (36099-26-0)

Guidance literature:

With 2,4,6-trimethyl-pyridine 1-oxide; trans-dioxo(5,10,15,20-tetramesitylporphirinato)ruthenium(VI); In benzene; at 30 ℃;

DOI:10.1016/S0040-4039(01)89017-1

upstream raw materials:

p-vinylbiphenyl

2-Bromo-4'-phenylacetophenone

methyldiphenyltelluronium tetraphenylborate

4-Phenylbenzaldehyde

Downstream raw materials:

(p-phenylphenyl)ethanolamine

2-(1,1'-biphenyl-4-yl)-2-trimethylsilyloxirane

2-(1,1'-biphenyl-4-yl)-2-(diphenyl(hydroxyl)methyl)oxirane

2-(1,1'-biphenyl-4-yl)-2-methyloxirane