Methanesulfonic acid, trifluoro-, 2-anthracenyl ester

Base Information

• Chemical Name: Methanesulfonic acid, trifluoro-, 2-anthracenyl ester
• CAS No.: 602297-32-5
• Molecular Formula: C15H9F3O3S
• Molecular Weight: 326.296
• Mol file: 602297-32-5.mol

Synonyms:

Chemical Property of Methanesulfonic acid, trifluoro-, 2-anthracenyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Methanesulfonic acid, trifluoro-, 2-anthracenyl ester

There total 1 articles about Methanesulfonic acid, trifluoro-, 2-anthracenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-bromoanthracene-9,10-dione (572-83-8) → 2-hydroxyanthracene trifluoromethanesulfonate (602297-32-5)

Guidance literature:

Multi-step reaction with 3 steps

1.1: NaBH₄ / propan-2-ol / 15 h / 25 °C

1.2: HCl / H₂O / 8 h / 75 °C

1.3: 54 percent / NaBH₄ / propan-2-ol / 20 h / Heating

2.1: n-BuLi / tetrahydrofuran / -78 - -15 °C

2.2: B(OBu)3 / tetrahydrofuran / -78 - 0 °C

2.3: 51 percent / H₂O₂; NaOH / methanol; H₂O / 3 h / 0 °C

3.1: 87 percent / Et₃N / CH₂Cl₂

With sodium tetrahydroborate; n-butyllithium; triethylamine; In tetrahydrofuran; dichloromethane; isopropyl alcohol;

DOI:10.1016/S0040-4039(02)02791-0

Reference yield: 84.0%

2-hydroxyanthracene trifluoromethanesulfonate (602297-32-5) + phenylboronic acid (98-80-6) → 2-phenylanthracene (1981-38-0)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In 1,4-dioxane; at 90 ℃; for 12h; Inert atmosphere;

DOI:10.1039/d0tc01122c

Reference yield: 69.0%

naphthalene-2-boronic acid (32316-92-0) + 2-hydroxyanthracene trifluoromethanesulfonate (602297-32-5) → 2-(naphthalen-2-yl)anthracene (15248-70-1)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In 1,4-dioxane; water; at 105 ℃; for 12h; Inert atmosphere;

DOI:10.1039/c5tc02254a

upstream raw materials:

2-bromoanthracene-9,10-dione

Downstream raw materials:

2-(naphthalen-2-yl)anthracene

2-phenylanthracene