Benzenemethanol, a-(1,1-dimethyl-3-butenyl)-2-methoxy-5-methyl-

Base Information

Chemical Name:Benzenemethanol, a-(1,1-dimethyl-3-butenyl)-2-methoxy-5-methyl-
CAS No.:603985-02-0
Molecular Formula:C15H22O2
Molecular Weight:234.338
Hs Code.:

Synonyms:

Suppliers and Price of Benzenemethanol, a-(1,1-dimethyl-3-butenyl)-2-methoxy-5-methyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzenemethanol, a-(1,1-dimethyl-3-butenyl)-2-methoxy-5-methyl-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Benzenemethanol, a-(1,1-dimethyl-3-butenyl)-2-methoxy-5-methyl-

There total 1 articles about Benzenemethanol, a-(1,1-dimethyl-3-butenyl)-2-methoxy-5-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 5497-67-6
2,2-dimethyl-4-pentenal

: 22002-45-5
2-bromo-4-methylanisole

: 603985-02-0
1-(2-methoxy-5-methyl-phenyl)-2,2-dimethyl-pent-4-en-1-ol

Guidance literature:: With lithium; In tetrahydrofuran; for 0.75h;
DOI:10.1016/S0040-4039(02)02734-X

Reference yield: 91.0%

: 603985-02-0
1-(2-methoxy-5-methyl-phenyl)-2,2-dimethyl-pent-4-en-1-ol

: 603985-03-1
1-(2-methoxy-5-methyl-phenyl)-2,2-dimethyl-pent-4-en-1-one

Guidance literature:: With silica gel; pyridinium chlorochromate; In dichloromethane; for 2h;
DOI:10.1016/S0040-4039(02)02734-X

Reference yield:

: 603985-02-0
1-(2-methoxy-5-methyl-phenyl)-2,2-dimethyl-pent-4-en-1-ol

: 81784-10-3
1S-(2'-hydroxy-5'-methylphenyl)-1,2,2-trimethylcyclopentane

Guidance literature:: Multi-step reaction with 10 steps

1.1: 91 percent / PCC; silica gel / CH₂Cl₂ / 2 h

2.1: 78 percent / tetrahydrofuran / 4 h

3.1: 84 percent / PCC; silica gel / CH₂Cl₂ / 24 h

4.1: 89 percent / NaBH₄ / methanol / 0 - 5 °C

5.1: 30 percent / EtCOOH / 36 h / 180 °C

6.1: 88 percent / PhCH=RuCl₂(PCy₃)2 / CH₂Cl₂ / 6 h / 20 °C

7.1: 99 percent / H₂ / Pd/C / ethanol / 6 h

8.1: LAH / diethyl ether / 1 h / 0 - 5 °C

8.2: PCC; silica gel / CH₂Cl₂ / 0.5 h

9.1: 80 percent / (Ph₃P)3RhCl / benzene / 24 h / 120 °C

10.1: 95 percent / BBr₃ / CH₂Cl₂ / 1.5 h / -40 - 20 °C

With sodium tetrahydroborate; lithium aluminium tetrahydride; hydrogen; silica gel; boron tribromide; propionic acid; pyridinium chlorochromate; palladium on activated charcoal; Wilkinson's catalyst; Grubbs catalyst first generation; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; benzene; 5.1: Claisen rearrangement;
DOI:10.1016/S0040-4039(02)02734-X