1,2,3-Cyclohexanetriol

Base Information

• Chemical Name: 1,2,3-Cyclohexanetriol
• CAS No.: 6286-43-7
• Molecular Formula: C6H12O3
• Molecular Weight: 132.159
• Mol file: 6286-43-7.mol

Synonyms:1,2,3-Trihydroxycyclohexane;NSC 10070;

Chemical Property of 1,2,3-Cyclohexanetriol

Chemical Property:

• Vapor Pressure: 0.017mmHg at 25°C
• Refractive Index: 1.58
• Boiling Point: 225.645 °C at 760 mmHg
• Flash Point: 105.596 °C
• Density: 1.357 g/cm³

Purity/Quality:

97% ^*data from raw suppliers

1,2,3-Cyclohexanetriol (cis- and trans- mixture) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2,3-Cyclohexanetriol

There total 34 articles about 1,2,3-Cyclohexanetriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

cyclohex-2-enyl hydroperoxide (4845-05-0) → rac-cyclohexane-1,2,3-triol (2630-65-1,6286-43-7,10515-21-6,13302-87-9,62445-01-6,123163-99-5,2630-64-0)

Guidance literature:

With osmium(VIII) oxide; water; In acetone; at 20 ℃; for 36h; diastereoselective reaction;

DOI:10.1055/s-0029-1217965

Reference yield: 90.0%

C12H14O6 (90399-57-8) → 1,2,3-trihydroxycyclohexane (6286-43-7)

Guidance literature:

With sodium tetrahydroborate;

DOI:10.1246/cl.1984.635

Reference yield: 89.6%

Cyclohex-2-enol (822-67-3) → 1,2,3-trihydroxycyclohexane (6286-43-7)

Guidance literature:

With potassium citrate; potassium carbonate; 4-methylmorpholine N-oxide; In water; acetonitrile; at 20 ℃; for 12.5h;

upstream raw materials:

Perbenzoic acid

chloroform

Cyclohex-2-enol

2-hydroxyresorcinol

Downstream raw materials:

cyclohexane-1,2,3-triol triacetate

rac-cyclohexane-1,2,3-triyl triacetate

(+/-)-1r,2,3t-tris-benzoyloxy-cyclohexane

(1R)-1r,2,3t-tris-benzoyloxy-cyclohexane