Phosphine sulfide, methyldiphenyl-, ion(1-), lithium

Base Information

Chemical Name:Phosphine sulfide, methyldiphenyl-, ion(1-), lithium
CAS No.:60703-90-4
Molecular Formula:C13H12PS.Li
Molecular Weight:238.219
Hs Code.:

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Chemical Property of Phosphine sulfide, methyldiphenyl-, ion(1-), lithium

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Technology Process of Phosphine sulfide, methyldiphenyl-, ion(1-), lithium

There total 1 articles about Phosphine sulfide, methyldiphenyl-, ion(1-), lithium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 917-54-4
methyllithium

: 3878-45-3
triphenylphosphine sulfide

: 60703-90-4
(C₆H₅)2P(S)CH₂^(1-)*Li⁽¹⁺⁾=((C₆H₅)2P(S)CH₂)Li

Guidance literature:

Reference yield: 80.0%

: 25749-29-5
(triphenylarsine)gold(I) chloride

: 60703-90-4
(C₆H₅)2P(S)CH₂^(1-)*Li⁽¹⁺⁾=((C₆H₅)2P(S)CH₂)Li

: 88272-19-9
{Au(CH₂P(S)(C₆H₅)2)}2

Guidance literature:: In diethyl ether; LiCH2P(S)(C6H5)2 added dropwise to an diethyl ether suspn. of (C6H5)3AsAuCl under N2 at -30°C; warmed to ambient temp., after 30 min yellow ppt. formed; recrystn. from hot toluene; elem. anal.;
DOI:10.1021/ja00315a062

Reference yield: 75.0%

: 39929-21-0
(tetrahydrothiophene)gold(I) chloride

: 60703-90-4
(C₆H₅)2P(S)CH₂^(1-)*Li⁽¹⁺⁾=((C₆H₅)2P(S)CH₂)Li

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: PPN{Au(MTP)2}

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; Li(CH2(S)PPh2) and Au(THT)Cl were stirred for 45 min in an inert atmosphere at -10 °C, slowly warmed to room temp., after 1 h the solvent was reduced to one-forth of its volume, addn. of (PPN)Cl in THF/methanol, stirred for 10 min, cooled;