Phosphorodichloridic acid, 2,2,2-trifluoro-1-[3-(trifluoromethyl)phenyl]ethyl ester

Base Information

• Chemical Name: Phosphorodichloridic acid, 2,2,2-trifluoro-1-[3-(trifluoromethyl)phenyl]ethyl ester
• CAS No.: 60988-80-9
• Molecular Formula: C9H5Cl2F6O2P
• Molecular Weight: 361.008
• Mol file: 60988-80-9.mol

Synonyms:

Chemical Property of Phosphorodichloridic acid, 2,2,2-trifluoro-1-[3-(trifluoromethyl)phenyl]ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphorodichloridic acid, 2,2,2-trifluoro-1-[3-(trifluoromethyl)phenyl]ethyl ester

There total 2 articles about Phosphorodichloridic acid, 2,2,2-trifluoro-1-[3-(trifluoromethyl)phenyl]ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

α-trifluoromethyl-m-trifluoromethylbenzyl alcohol (721-36-8) → α-trifluoromethyl-m-trifluoromethylbenzyl dichlorophosphate (60988-80-9) + bis(α-trifluoromethyl-m-trifluoromethylbenzyl)chlorophosphate

Guidance literature:

With calcium chloride; trichlorophosphate; at 140 ℃; for 80h; Product distribution; various reaction conditions;

DOI:10.1007/BF00956527

Reference yield:

→ α-trifluoromethyl-m-trifluoromethylbenzyl dichlorophosphate (60988-80-9)

Guidance literature:

d. Alkohol, POCl3;

DOI:10.1007/BF00921440

Reference yield: 29.0%

α,α-dimethyl-ω-hydroperfluoropentanol (2673-15-6) + α-trifluoromethyl-m-trifluoromethylbenzyl dichlorophosphate (60988-80-9) → Phosphorochloridic acid 2,2,3,3,4,4,5,5-octafluoro-1,1-dimethyl-pentyl ester 2,2,2-trifluoro-1-(3-trifluoromethyl-phenyl)-ethyl ester (132587-76-9,132587-84-9)

Guidance literature:

With calcium chloride; at 175 ℃;

upstream raw materials:

α-trifluoromethyl-m-trifluoromethylbenzyl alcohol

Downstream raw materials:

Phosphorochloridic acid 2,2,3,3,4,4,5,5-octafluoro-1,1-dimethyl-pentyl ester 2,2,2-trifluoro-1-(3-trifluoromethyl-phenyl)-ethyl ester