Diethyl diphenylmethylamidophosphate

Base Information

• Chemical Name: Diethyl diphenylmethylamidophosphate
• CAS No.: 57673-92-4
• Molecular Formula: C17H22NO3P
• Molecular Weight: 319.3352
• European Community (EC) Number: 654-231-2
• NSC Number: 100766
• DSSTox Substance ID: DTXSID00295252
• Nikkaji Number: J1.219.654G
• Wikidata: Q82035072
• Mol file: 57673-92-4.mol

Synonyms:Diethyl diphenylmethylamidophosphate;57673-92-4;Diethyl benzhydrylphosphoramidate;diethyl(diphenylmethyl)phosphoramidate;N-diethoxyphosphoryl-1,1-diphenylmethanamine;NSC100766;DTXSID00295252;AKOS024332905;NSC-100766

Chemical Property of Diethyl diphenylmethylamidophosphate

Chemical Property:

• Vapor Pressure: 2.72E-07mmHg at 25°C
• Boiling Point: 420.9°Cat760mmHg
• Flash Point: 208.3°C
• PSA: 57.37000
• Density: 1.135g/cm³
• LogP: 4.93760
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 319.13373056
• Heavy Atom Count: 22
• Complexity: 324

Purity/Quality:

99%min ^*data from raw suppliers

DIETHYL DIPHENYLMETHYLAMIDOPHOSPHATE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCOP(=O)(NC(C1=CC=CC=C1)C2=CC=CC=C2)OCC

Technology Process of Diethyl diphenylmethylamidophosphate

There total 3 articles about Diethyl diphenylmethylamidophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

trimethyl(phenyl)stannane (934-56-5) + N-(diethoxyphosphoryl)benzylideneimine (85522-68-5) → N-(diethoxyphosphoryl)(diphenylmethyl)amine (57673-92-4)

Guidance literature:

bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; In tetrahydrofuran; at 60 ℃; for 20h;

DOI:10.1016/S0040-4039(99)01857-2

Reference yield: 84.0%

trimethyl(phenyl)stannane (934-56-5) + N-(Diethoxyphosphoryl)benzylideneimine (180399-94-4) → N-(diethoxyphosphoryl)(diphenylmethyl)amine (57673-92-4)

Guidance literature:

With bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; In tetrahydrofuran; at 60 ℃; for 20h;

DOI:10.1016/S0040-4020(03)00586-6

Reference yield:

bromobenzene (108-86-1,52753-63-6) + ethyl-formimidate (23175-48-6) → N-(diethoxyphosphoryl)(diphenylmethyl)amine (57673-92-4)

Guidance literature:

With magnesium; In diethyl ether; for 2h; Ambient temperature;

upstream raw materials:

bromobenzene

ethyl-formimidate

trimethyl(phenyl)stannane

N-(diethoxyphosphoryl)benzylideneimine

Refernces

• 1、 Oi, Shuichi,Moro, Mitsutoshi,Fukuhara, Hiroe,Kawanishi, Takanori,Inoue, Yoshio. "Rhodium-catalyzed arylation and alkenylation of imines with organostannanes". . p. 9259 - 9262. Retrieved 2007/10/03.