2-Propenoic acid, 3-(phenylsulfinyl)-, methyl ester

Base Information

Chemical Name:2-Propenoic acid, 3-(phenylsulfinyl)-, methyl ester
CAS No.:63068-30-4
Molecular Formula:C10H10O3S
Molecular Weight:210.25000
Hs Code.:

Synonyms:Methyl-benzolsulfinylacrylat;(E)-3-Benzenesulfinyl-acrylic acid methyl ester;

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Chemical Property of 2-Propenoic acid, 3-(phenylsulfinyl)-, methyl ester

Chemical Property:

Melting Point:80 - 81 °C
PSA：62.58000
LogP:2.34660

Purity/Quality:

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Technology Process of 2-Propenoic acid, 3-(phenylsulfinyl)-, methyl ester

There total 3 articles about 2-Propenoic acid, 3-(phenylsulfinyl)-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 62076-10-2,4170-71-2
(tert-butylsulfinyl)benzene

: 922-67-8
propynoic acid methyl ester

: 63068-30-4
2-carbomethoxyethenyl phenyl sulfoxide

Guidance literature:: With 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In toluene; at 110 ℃; for 15h; Schlenk technique; Inert atmosphere;
DOI:10.1002/adsc.201500368

Reference yield:

: 108-98-5
thiophenol

: 63068-30-4
2-carbomethoxyethenyl phenyl sulfoxide

Guidance literature:: Multi-step reaction with 2 steps

1.1: perchloric acid; acetic acid; acetic anhydride / 24 h / 20 °C / Cooling with ice

1.2: 8 h / 0 - 20 °C

2.1: bis(dibenzylideneacetone)-palladium⁽⁰⁾; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene / toluene / 15 h / 110 °C / Schlenk technique; Inert atmosphere

With perchloric acid; acetic anhydride; acetic acid; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In toluene;
DOI:10.1002/adsc.201500368