Benzene;titanium

Base Information

• Chemical Name: Benzene;titanium
• CAS No.: 52462-43-8
• Molecular Formula: C12H13Ti-11
• Molecular Weight: 205.1014
• Mol file: 52462-43-8.mol

Synonyms:

Chemical Property of Benzene;titanium

Chemical Property:

• Vapor Pressure: 93.7mmHg at 25°C
• Boiling Point: 80.7°Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 204.0418411
• Heavy Atom Count: 13
• Complexity: 15.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=CC=C1.C1=CC=CC=C1.[Ti]

Technology Process of Benzene;titanium

There total 6 articles about Benzene;titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

titanium tetrachloride (7550-45-0) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → bis(η6-benzene)titanium (52462-43-8)

Guidance literature:

With potassium triethylborohydride; for 2h; Sonication;

DOI:10.1002/chem.201500737

Reference yield: 11.0%

titanium tetrachloride (7550-45-0) → bis(η6-benzene)titanium (52462-43-8)

Guidance literature:

With benzene; In benzene; Sonication; TiCl4 under Ar dissolved in benzene is immersed in an ultrasonic bath for 60 min at room temp., addn. of K(BEt3H) in benzene, for 60 min in the ultrasonic bath; filtn. of the ppt., washing (benzene), removal the solvent of the filtrate, dissolving the residue in pentane, filtn., removal the pentane, recrystn. of the residue (pentane);

DOI:10.1016/0304-5102(92)80250-K

Reference yield:

titanium (7440-32-6) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → bis(η6-benzene)titanium (52462-43-8)

Guidance literature:

In solid matrix; condensation of vaporized Ti in high vac. with solid benzene matrix cooled with liq. N2;

DOI:10.1023/A:1016080716618

upstream raw materials:

titanium

Cyclohepta-1,3,5-triene

benzene

titanium tetrachloride