7550-45-0Relevant articles and documents
Wardlaw, W.,Clews, F. H.
, p. 1093 - 1103 (1920)
Jakubec, I.,Vondrak, J.,Bludska, J.
, p. 447 - 452 (1989)
Jakubec, I.,Vondrak, J.,Bludska, J.
, p. 505 - 510 (1989)
Rhead, E. L.
, p. 1491 - 1495 (1906)
Heterogeneous Catalysis in Solution. Part 27. - Reaction between Titanium(III) and Triiodide Ions Catalysed by Platinum
Xiao, Shaorong,Spiro, Michael
, p. 1983 - 1986 (1994)
The rate of the reaction between titanium(III) chloride and triiodide ions in an acid chloride medium has been studied in the absence and presence of a rotating platinum disk.At low concentrations of triiodide the catalytic rate at platinum was found to be first order in I3(-), zero order with respect to Ti(III) and H(+), and proportional to the square root of the rotation speed of the disk.These results pointed to diffusion-controlled catalysis, as did the low activation energy of 19 kJ mol-1 as compared with 40 kJ mol-1 for the uncatalysed reaction.All these findings are consistent with an electrochemical interpretation of the catalytic mechanism, as was shown by the current-potential curves determined for the two reactants at the same reduced platinum surface.Provided that the voltammograms for Ti(III) had been carried out in the presence of the same concentration of KI as in the reaction mixtures, the rates and mixture potentials determined electrochemically agreed well with the catalytic rates and potentials measured experimentally.The fact that quite different results were obtained when no KI was present in the TiCl3 solution provides further confirmation for the modified form of the additivity principle.
The low temperature synthesis of metal oxides by novel hydrazine method
Rane,Uskaikar,Pednekar,Mhalsikar
, p. 627 - 638 (2008/10/09)
The hydroxide, oxalate and citrate precursors of the metal oxides such as γ-Fe2O3, (MnZn)Fe2O4, Cu(K)Fe2O4, BaTiO3, La(Sr)MnO3, La(Sr)AlO3, La/Gd(Ca/Ba/Sr)C
Electron deficient carbon-titanium triple bonds: Formation of triplet XC÷TiX3 methylidyne complexes
Lyon, Jonathan T.,Andrews, Lester
, p. 9858 - 9863 (2008/10/09)
Laser-ablated titanium atoms react with CX4 (X = F and Cl) to produce triplet state XC÷TiX3 complexes trapped in an argon matrix. Products are identified by their infrared spectra and comparison to theoretically predicted vibrations.