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Product FOB Price Min.Order Supply Ability Supplier
Manufactory supply bulk Titanium tetrachloride
Cas No: 7550-45-0
USD $ 1.0-10.0 / Kilogram 1 Kilogram 100 Metric Ton/Year Kono Chem Co.,Ltd Contact Supplier
cas7550-45-0 99.9percent min Titanium Tetrachloride supplier in China
Cas No: 7550-45-0
No Data 1 Metric Ton 10000 Metric Ton/Year Simagchem Corporation Contact Supplier
Top purity Titanium(IV) chloride with high quality and best price cas:7550-45-0
Cas No: 7550-45-0
USD $ 3.0-10.0 / Kilogram 1 Kilogram 99999 Kilogram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
Fresh In Stock:Titanium Tetrachloride with BEST PRICE
Cas No: 7550-45-0
USD $ 1.0-1.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Scale Chemical Corporation Contact Supplier
CHemwill -- Titanium tetrachloride
Cas No: 7550-45-0
USD $ 1.0-1.0 / Metric Ton 1 Metric Ton 5 Metric Ton/Day Chemwill Asia Co., Ltd. Contact Supplier
TitaniuM(IV) Chloride (14% in DichloroMethane, ca. 1.0Mol/L)
Cas No: 7550-45-0
No Data 1 Kilogram Metric Ton/Day Henan Allgreen Chemical Co.,Ltd Contact Supplier
Titanium tetrachloride
Cas No: 7550-45-0
USD $ 2.0-2.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Hangzhou Dayangchem Co., Ltd. Contact Supplier
Wholesale 7550-45-0 Titanium tetrachloride with best offer
Cas No: 7550-45-0
USD $ 1.0-1.0 / Kilogram 1 Kilogram 50 Kilogram/Month HENAN SUNLAKE ENTERPRISE CORPORATION Contact Supplier
Top sale 7550-45-0 Titanium tetrachloride with best price
Cas No: 7550-45-0
USD $ 1000.0-1500.0 / Kilogram 1 Kilogram 100 Metric Ton/Month Crovell Biotech (Hebei) Co., Ltd. Contact Supplier
Titanium (IV) chloride, 99%
Cas No: 7550-45-0
No Data 1 Metric Ton 10 Metric Ton/Day Henan Tianfu Chemical Co., Ltd. Contact Supplier

7550-45-0 Usage

Uses

Titanium tetrachloride is used to prepare titanium dioxide and most other titanium compounds. It also is used in making iridescent glass; arificial pearls; and smoke screens. The compound is a polymerization catalyst.

Reactivity Profile

Titanium tetrachloride acts as an acid in aqueous solution. During the reduction of Titanium tetrachloride to titanium metal with potassium, an explosion occurred. The system had been heated to 90°C [Walter and Mandell 1967]. Addition directly to tetrahydrofuran caused a violent exothermic reaction [Inorg. Syn., 1982, 21, 135]. Ethylene can polymerize at low pressure if catalyzed by titanium halides. (Sundaram, K. M, M. M. Shreehan, E. F. Olszewski. thylene. Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. 2001.)

Health Hazard

Titanium tetrachloride is a highly corrosive, acute irritant to the skin, eyes, mucous membranes and the respiratory tract. It is capable of causing death or permanent injury due to exposures encountered in normal use. Even short contact may lead to eye inflammation which may result in corneal opacities.

General Description

A colorless fuming liquid with a pungent odor. Corrosive to metals and tissue. Very toxic by inhalation.

Hazard

Toxic by inhalation, strong irritant to skin and tissue.

Fire Hazard

Material will react with water to produce hydrochloric acid. Titanium tetrachloride may ignite other combustible materials (e.g., wood, oil, etc.). Flammable, poisonous gases may accumulate in tanks and hopper cars. Runoff to sewer may create fire or explosion hazard. Reacts strongly with water to release hydrochloric acid and heat. Avoid water, moist air. Stable in concentrated aqueous solutions. Avoid contact with moisture; the chemical absorbs moisture from air and evolves dense white fumes.

Uses

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.1

Physical Properties

Colorless or yellow liquid; penetrating acid odor; absorbs moisture from air; produces dense white fumes; density 1.73 g/mL; freezes at –25°C; boils at 136.5°C; critical temperature 464.8°C; critical pressure 46.6 atm; critical volume 339 cm3/mol; reacts with water forming TiO2 and HCl; soluble in ethanol

Uses

manufacture of titanium compounds, iridescent glass and artificial pearls. Formerly used with potassium bitartrate as a mordant in textile industry, and with dyewoods in dyeing leather; also as smoke-producing screen with ammonia.

Chemical Properties

Colorless liquid. Fumes strongly when exposed to moist air, forming a dense and persistent white cloud. Soluble in dilute hydrochloric acid; soluble in water with evolution of heat; concentrated aqueous solutions are stable and corrosive; dilute solutions

Purification Methods

Reflux it with mercury or a small amount of pure copper turnings to remove the last traces of colour [due to FeCl3 and VCl4], then distil it under N2 in an all-glass system, taking precautions to exclude moisture. Clabaugh et al. [J Res Nat Bur Stand 55 261 1955] removed organic material by adding aluminium chloride hexahydrate as a slurry with an equal amount of water (the slurry being ca one-fiftieth the weight of TiCl4), refluxed it for 2-6hours while bubbling in chlorine, the excess of which is subsequently removed by passing a stream of clean dry air. The TiCl4 is then distilled, refluxed with copper and again distilled, taking precautions to exclude moisture. Volatile impurities are then removed using a technique of freezing, pumping and melting. The titanium tetrachloride 2-tetrahydrofuran complex [Beilstein 17/1 V 33.] M 333.9, has m 126-128o and is easier to handle than TiCl4 [Abrahamson et al. Organometallics 3 1379 1984]. [Baxter & Fertig J Am Chem Soc 45 1228 1923, Baxter & Butler J Am Chem Soc 48 3117 1926.] HARMFUL VAPOURS.

Preparation

Titanium tetrachloride is prepared by heating titanium dioxide or the ores ilmenite or rutile with carbon to red heat in a stream of chlorine. When ilmetite is used, ferric chloride also is produced. Titanium tetrachloride is separated from ferric chloride and other impurities by fractionation.
InChI:InChI=1/4ClH.Ti/h4*1H;/q;;;;+4/p-4

7550-45-0 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (345695)  Titanium(IV)chloridesolution  1.0 M in toluene 7550-45-0 345695-4X100ML 2,058.03CNY Detail
Sigma-Aldrich (249866)  Titanium(IV)chloridesolution  1.0 M in methylene chloride 7550-45-0 249866-100ML 647.01CNY Detail
Sigma-Aldrich (404985)  Titanium(IV)chloridesolution  0.09 M in 20% HCl 7550-45-0 404985-4X100ML 2,391.48CNY Detail
Alfa Aesar (22979)  Titanium(IV) chloride, 99.99% (metals basis)    7550-45-0 100g 1578.0CNY Detail
Alfa Aesar (22979)  Titanium(IV) chloride, 99.99% (metals basis)    7550-45-0 25g 450.0CNY Detail
Alfa Aesar (22979)  Titanium(IV) chloride, 99.99% (metals basis)    7550-45-0 2.5g 81.0CNY Detail
Alfa Aesar (14713)  Titanium(IV) chloride, 99.0% min, typically 99.6%    7550-45-0 *3x1L 2145.0CNY Detail
Alfa Aesar (14713)  Titanium(IV) chloride, 99.0% min, typically 99.6%    7550-45-0 *3x1L 1857.0CNY Detail
Alfa Aesar (14713)  Titanium(IV) chloride, 99.0% min, typically 99.6%    7550-45-0 1L 685.0CNY Detail
Alfa Aesar (14713)  Titanium(IV) chloride, 99.0% min, typically 99.6%    7550-45-0 100ml 233.0CNY Detail
Alfa Aesar (H31808)  Titanium(IV) chloride, 1M soln. in toluene    7550-45-0 500ml 1979.0CNY Detail
Alfa Aesar (H31808)  Titanium(IV) chloride, 1M soln. in toluene    7550-45-0 100ml 591.0CNY Detail

7550-45-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Titanium(IV) chloride

1.2 Other means of identification

Product number -
Other names Titanium tetrachloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7550-45-0 SDS

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