2,5-Hexadienoic acid, 6-[[(2E,4E,6S,7S,8R,9S,10E)-7,9-dimethoxy-3,6,8-trimethyl-1-oxo-11- phenyl-2,4,10-undecatrienyl][[2-(trimethylsilyl)ethoxy]carbonyl]amino]-, (2Z,5Z)-

Base Information

Chemical Name:2,5-Hexadienoic acid, 6-[[(2E,4E,6S,7S,8R,9S,10E)-7,9-dimethoxy-3,6,8-trimethyl-1-oxo-11- phenyl-2,4,10-undecatrienyl][[2-(trimethylsilyl)ethoxy]carbonyl]amino]-, (2Z,5Z)-
CAS No.:633302-57-5
Molecular Formula:C34H49NO7Si
Molecular Weight:611.851
Hs Code.:

2,5-Hexadienoic acid,
6-[[(2E,4E,6S,7S,8R,9S,10E)-7,9-dimethoxy-3,6,8-trimethyl-1-oxo-11-
phenyl-2,4,10-undecatrienyl][[2-(trimethylsilyl)ethoxy]carbonyl]amino]-,
(2Z,5Z)-

Synonyms:

Suppliers and Price of 2,5-Hexadienoic acid, 6-[[(2E,4E,6S,7S,8R,9S,10E)-7,9-dimethoxy-3,6,8-trimethyl-1-oxo-11- phenyl-2,4,10-undecatrienyl][[2-(trimethylsilyl)ethoxy]carbonyl]amino]-, (2Z,5Z)-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2,5-Hexadienoic acid, 6-[[(2E,4E,6S,7S,8R,9S,10E)-7,9-dimethoxy-3,6,8-trimethyl-1-oxo-11- phenyl-2,4,10-undecatrienyl][[2-(trimethylsilyl)ethoxy]carbonyl]amino]-, (2Z,5Z)-

Chemical Property:

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Technology Process of 2,5-Hexadienoic acid, 6-[[(2E,4E,6S,7S,8R,9S,10E)-7,9-dimethoxy-3,6,8-trimethyl-1-oxo-11- phenyl-2,4,10-undecatrienyl][[2-(trimethylsilyl)ethoxy]carbonyl]amino]-, (2Z,5Z)-

There total 10 articles about 2,5-Hexadienoic acid, 6-[[(2E,4E,6S,7S,8R,9S,10E)-7,9-dimethoxy-3,6,8-trimethyl-1-oxo-11- phenyl-2,4,10-undecatrienyl][[2-(trimethylsilyl)ethoxy]carbonyl]amino]-, (2Z,5Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: ((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-((1Z,4Z)-6-oxo-hexa-1,4-dienyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

: 633302-57-5
(2Z,5Z)-6-[((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-(2-trimethylsilanyl-ethoxycarbonyl)-amino]-hexa-2,5-dienoic acid

Guidance literature:: With sodium chlorite; sodium dihydrogenphosphate;
DOI:10.1071/CH03026

Reference yield:

: 633302-51-9
7-(tert-butyl-dimethyl-silanyloxy)-hepta-2,5-diyn-1-ol

: 633302-57-5
(2Z,5Z)-6-[((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-(2-trimethylsilanyl-ethoxycarbonyl)-amino]-hexa-2,5-dienoic acid

Guidance literature:: Multi-step reaction with 9 steps

1: hydrogen; ethylenediamine / P₂-Ni

2: Dess-Martin periodinane; 2,6-lutidine / 0 °C

3: NaClO₂; NaH₂PO₄

4: NaH; (PhO)2P(O)N₃ / 0 °C

5: 65 percent / toluene / 110 °C

6: 37 percent / sodium hexamethyldisilazide / tetrahydrofuran / -78 °C

7: 87 percent / HF*pyridine; pyridine

8: Dess-Martin periodinane; 2,6-lutidine / 0 °C

9: NaClO₂; NaH₂PO₄

With pyridine; 2,6-dimethylpyridine; sodium chlorite; sodium dihydrogenphosphate; diphenyl phosphoryl azide; hydrogen; sodium hexamethyldisilazane; sodium hydride; Dess-Martin periodane; pyridine hydrogenfluoride; ethylenediamine; P₂-Ni; In tetrahydrofuran; toluene; 2: Dess-Martin oxidation / 5: Curtius rearrangement / 8: Dess-Martin oxidation;
DOI:10.1071/CH03026

Reference yield:

: 633302-49-5
(2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl chloride

: 633302-57-5
(2Z,5Z)-6-[((2E,4E,10E)-(6S,7S,8R,9S)-7,9-Dimethoxy-3,6,8-trimethyl-11-phenyl-undeca-2,4,10-trienoyl)-(2-trimethylsilanyl-ethoxycarbonyl)-amino]-hexa-2,5-dienoic acid

Guidance literature:: Multi-step reaction with 4 steps

1: 37 percent / sodium hexamethyldisilazide / tetrahydrofuran / -78 °C

2: 87 percent / HF*pyridine; pyridine

3: Dess-Martin periodinane; 2,6-lutidine / 0 °C

4: NaClO₂; NaH₂PO₄

With pyridine; 2,6-dimethylpyridine; sodium chlorite; sodium dihydrogenphosphate; sodium hexamethyldisilazane; Dess-Martin periodane; pyridine hydrogenfluoride; In tetrahydrofuran; 3: Dess-Martin oxidation;
DOI:10.1071/CH03026