1,1'-Biphenyl, 4-bromo-4'-butyl-

Base Information

• Chemical Name: 1,1'-Biphenyl, 4-bromo-4'-butyl-
• CAS No.: 63619-54-5
• Molecular Formula: C16H17Br
• Molecular Weight: 289.215
• Mol file: 63619-54-5.mol

Synonyms:1-bromo-4-(4-butylphenyl)benzene;

Chemical Property of 1,1'-Biphenyl, 4-bromo-4'-butyl-

Chemical Property:

• PSA: 0.00000
• Density: 1.221
• LogP: 5.45870
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

4-Bromo-4'-butyl-1,1'-biphenyl 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 4-Bromo-4'-butyl-1,1'-biphenyl is a useful research chemical compound.

Technology Process of 1,1'-Biphenyl, 4-bromo-4'-butyl-

There total 3 articles about 1,1'-Biphenyl, 4-bromo-4'-butyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + 4-(4-bromophenyl)bromobenzene (92-86-4) → biphenyl (92-52-4,1594-86-1) + 4-bromo-1,1'-biphenyl (92-66-0) + 4-bromo-4'-(n-butyl)-2,2'-biphenyl (63619-54-5)

Guidance literature:

n-butyllithium; 4-(4-bromophenyl)bromobenzene; In tetrahydrofuran; hexane; at 0 ℃; for 0.166667h;

With methanol; In tetrahydrofuran; hexane; at 0 ℃; for 0.166667h;

DOI:10.1021/ol8015572

Reference yield:

4-(4-bromophenyl)bromobenzene (92-86-4) → 4-bromo-1,1'-biphenyl (92-66-0) + 4-bromo-4'-(n-butyl)-2,2'-biphenyl (63619-54-5)

Guidance literature:

4-(4-bromophenyl)bromobenzene; With n-butyllithium; In tetrahydrofuran; hexane; at 24 ℃; for 0.166667h;

With methanol; In tetrahydrofuran; hexane; at 24 ℃; for 0.166667h;

DOI:10.3762/bjoc.5.16

Reference yield:

4-(4-bromophenyl)bromobenzene (92-86-4) → biphenyl (92-52-4,1594-86-1) + 4-bromo-1,1'-biphenyl (92-66-0) + 4-bromo-4'-(n-butyl)-2,2'-biphenyl (63619-54-5)

Guidance literature:

4-(4-bromophenyl)bromobenzene; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.166667h;

With methanol; In tetrahydrofuran; hexane; at 0 ℃; for 0.166667h;

DOI:10.3762/bjoc.5.16

upstream raw materials:

n-butyllithium

4-(4-bromophenyl)bromobenzene

Downstream raw materials:

(4'-n-butylbiphen-4-yl)boronic acid

1,2,4,5-tetrakis(4'-butyl-biphenyl-4-ethynyl)benzene

Refernces

• 1、 Nagaki, Aiichiro,Takabayashi, Naofumi,Tomida, Yutaka,Yoshida, Jun-ichi. "Selective monolithiation of dibromobiaryls using microflow systems". supporting information; experimental part. p. 3937 - 3940. Retrieved 2009/06/18.