(E)-Chloro-N-methyl-N-phenylmethaniminium chloride

Base Information

• Chemical Name: (E)-Chloro-N-methyl-N-phenylmethaniminium chloride
• CAS No.: 63640-93-7
• Molecular Formula: C8H9ClN.Cl
• Molecular Weight: 190.072
• DSSTox Substance ID: DTXSID90506021
• Mol file: 63640-93-7.mol

Synonyms:63640-93-7;(E)-Chloro-N-methyl-N-phenylmethaniminium chloride;SCHEMBL8006145;DTXSID90506021

Chemical Property of (E)-Chloro-N-methyl-N-phenylmethaniminium chloride

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 189.0112047
• Heavy Atom Count: 11
• Complexity: 125

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[N+](=CCl)C1=CC=CC=C1.[Cl-]

Technology Process of (E)-Chloro-N-methyl-N-phenylmethaniminium chloride

There total 2 articles about (E)-Chloro-N-methyl-N-phenylmethaniminium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-methyl-N-phenylformamide (93-61-8) → (N-methyl-N-phenyl)chloromethaniminium chloride (63640-93-7)

Guidance literature:

With oxalyl dichloride; In chloroform; Ambient temperature;

Reference yield:

phosgene (75-44-5) + N-methyl-N-phenylformamide (93-61-8) → (N-methyl-N-phenyl)chloromethaniminium chloride (63640-93-7)

Guidance literature:

With diethyl ether;

DOI:10.1002/hlca.19590420526

Reference yield: 42.0%

Na{(η5-CH3C5H4)(CO)2Mn(SiMePh2)} + (N-methyl-N-phenyl)chloromethaniminium chloride (63640-93-7) → methylcyclopentadienyl manganese(I) tricarbonyl + MeCp(CO)2Mn(H)SiPh2Me + (CH3)C5H4Mn(CO)2CHN(C6H5)(CH3) + chloromethyldiphenylsilane (144-79-6)

Guidance literature:

In tetrahydrofuran; byproducts: NaCl; Addn. of (PhMeNCHCl)Cl to soln. of Mn-complex under N2 with stirring, color changes to green.; Filtn., evapn. of solvent, dissolving in toluene, column chromy. (SiO2, 5°C, toluene), evapn. of the second zone in vac., recrystn. (pentane, -78°C), elem. anal.;

upstream raw materials:

phosgene

N-methyl-N-phenylformamide

Downstream raw materials:

(Z)-1,2-Dichloro-N,N'-dimethyl-N,N'-diphenyl-ethene-1,2-diamine

(E)-1,2-Dichloro-N,N'-dimethyl-N,N'-diphenyl-ethene-1,2-diamine

N-methyl-N-phenyl-N'-p-tolylformamidine

C₁₄H₁₃ClN₂