Kalihinol E

Base Information

Chemical Name:Kalihinol E
CAS No.:93528-15-5
Molecular Formula:
Molecular Weight:
Hs Code.:

Synonyms:

Suppliers and Price of Kalihinol E

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Kalihinol E

Chemical Property:

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Technology Process of Kalihinol E

There total 35 articles about Kalihinol E which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 252962-64-4
5,10-bisformamidokalihinol A

: 91294-83-6,93528-15-5,110043-50-0
kalihinol-A

Guidance literature:: With pyridine; p-toluenesulfonyl chloride; In dichloromethane; at 20 ℃; for 12h;
DOI:10.1039/c1cc16468f

Reference yield:

: 440333-45-9
C₂₄H₃₆O₆

: 91294-83-6,93528-15-5,110043-50-0
kalihinol-A

Guidance literature:: Multi-step reaction with 23 steps

1.1: 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine / dichloromethane / 0.08 h / 0 °C

2.1: diisobutylaluminium hydride / hexane; toluene / 0.17 h / -78 °C

3.1: pyridine / 0.5 h / 20 °C

4.1: iodonium(di-γ-collidine) perchlorate / dichloromethane / 4 h / 20 °C

5.1: triethyl borane; tri-n-butyl-tin hydride / tetrahydrofuran / 1 h / -78 °C

6.1: palladium 10% on activated carbon; hydrogen / methanol / 2.5 h / 20 °C

7.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.17 h / 20 °C

8.1: tetrahydrofuran / 0.17 h / 0 °C

9.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 20 °C

10.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.17 h / -78 °C

11.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

12.1: N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

12.2: 2 h / -78 - 20 °C

13.1: tetrabutyl ammonium fluoride / 2 h / 20 °C

14.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

15.1: disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 3 h / 0 °C

16.1: sodium azide; ammonium chloride / methanol; water / 10 h / Reflux

17.1: lithium hexamethyldisilazane / tetrahydrofuran / 3 h / -78 °C

18.1: copper(II) bis(trifluoromethanesulfonate) / acetonitrile / 3 h / 20 °C / Molecular sieve

19.1: sodium tetrahydroborate; nickel(II) chloride hexahydrate / tetrahydrofuran; methanol / 3.17 h / 0 - 20 °C

20.1: lithium triethylborohydride / tetrahydrofuran / 1.5 h / 0 - 40 °C

21.1: naphthalene; lithium / tetrahydrofuran / 1 h / -78 - 20 °C

22.1: dichloromethane / 4 h / 20 °C

23.1: pyridine; p-toluenesulfonyl chloride / dichloromethane / 12 h / 20 °C

With pyridine; 1H-imidazole; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; disodium hydrogenphosphate; n-butyllithium; sodium azide; naphthalene; nickel(II) chloride hexahydrate; 1,1,1,3,3,3-hexachloro-propan-2-one; triethyl borane; iodonium(di-γ-collidine) perchlorate; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; tri-n-butyl-tin hydride; lithium; copper(II) bis(trifluoromethanesulfonate); diisobutylaluminium hydride; lithium triethylborohydride; sodium hydrogencarbonate; ammonium chloride; Dess-Martin periodane; p-toluenesulfonyl chloride; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; 14.1: intramolecular Diels-Alder reaction;
DOI:10.1039/c1cc16468f

Reference yield:

: 440333-31-3
(2S,3R,6R)-3-acetoxy-2-(3-benzyloxypropyl)-6-chloro-3,7-dimethyl-7-octenyl acetate

: 91294-83-6,93528-15-5,110043-50-0
kalihinol-A

Guidance literature:: Multi-step reaction with 22 steps

1.1: diisobutylaluminium hydride / hexane; toluene / 0.17 h / -78 °C

2.1: pyridine / 0.5 h / 20 °C

3.1: iodonium(di-γ-collidine) perchlorate / dichloromethane / 4 h / 20 °C

4.1: triethyl borane; tri-n-butyl-tin hydride / tetrahydrofuran / 1 h / -78 °C

5.1: palladium 10% on activated carbon; hydrogen / methanol / 2.5 h / 20 °C

6.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.17 h / 20 °C

7.1: tetrahydrofuran / 0.17 h / 0 °C

8.1: 1H-imidazole / N,N-dimethyl-formamide / 1 h / 20 °C

9.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.17 h / -78 °C

10.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

11.1: N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

11.2: 2 h / -78 - 20 °C

12.1: tetrabutyl ammonium fluoride / 2 h / 20 °C

13.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C

14.1: disodium hydrogenphosphate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 3 h / 0 °C

15.1: sodium azide; ammonium chloride / methanol; water / 10 h / Reflux

16.1: lithium hexamethyldisilazane / tetrahydrofuran / 3 h / -78 °C

17.1: copper(II) bis(trifluoromethanesulfonate) / acetonitrile / 3 h / 20 °C / Molecular sieve

18.1: sodium tetrahydroborate; nickel(II) chloride hexahydrate / tetrahydrofuran; methanol / 3.17 h / 0 - 20 °C

19.1: lithium triethylborohydride / tetrahydrofuran / 1.5 h / 0 - 40 °C

20.1: naphthalene; lithium / tetrahydrofuran / 1 h / -78 - 20 °C

21.1: dichloromethane / 4 h / 20 °C

22.1: pyridine; p-toluenesulfonyl chloride / dichloromethane / 12 h / 20 °C

With pyridine; 1H-imidazole; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium tetrahydroborate; disodium hydrogenphosphate; n-butyllithium; sodium azide; naphthalene; nickel(II) chloride hexahydrate; triethyl borane; iodonium(di-γ-collidine) perchlorate; palladium 10% on activated carbon; tetrabutyl ammonium fluoride; hydrogen; tri-n-butyl-tin hydride; lithium; copper(II) bis(trifluoromethanesulfonate); diisobutylaluminium hydride; lithium triethylborohydride; sodium hydrogencarbonate; ammonium chloride; Dess-Martin periodane; p-toluenesulfonyl chloride; 3-chloro-benzenecarboperoxoic acid; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; hexane; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; 13.1: intramolecular Diels-Alder reaction;
DOI:10.1039/c1cc16468f