(E)-5-Decen-1-yl acetate

Base Information

• Chemical Name: (E)-5-Decen-1-yl acetate
• CAS No.: 38421-90-8
• Molecular Formula: C12H22 O2
• Molecular Weight: 198.305
• Hs Code.: 2915390090
• European Community (EC) Number: 253-923-8
• UNII: 7NJ786556E
• DSSTox Substance ID: DTXSID0035295
• Nikkaji Number: J118.252H,J689K
• Metabolomics Workbench ID: 3848
• Mol file: 38421-90-8.mol

Synonyms:5-decenyl acetate

Chemical Property of (E)-5-Decen-1-yl acetate

Chemical Property:

• Vapor Pressure: 0.192mmHg at 25°C
• Refractive Index: 1.4393 (19℃)
• Boiling Point: 210.5°Cat760mmHg
• Flash Point: 62.2°C
• PSA: 26.30000
• Density: 0.886g/cm³
• LogP: 3.46620
• Storage Temp.: -20°C
• Solubility.: Chloroform (Slightly), Ethyl Acetate (Slightly)
• XLogP3: 3.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 198.161979940
• Heavy Atom Count: 14
• Complexity: 162

Purity/Quality:

93% ^*data from raw suppliers

(E)-5-Decen-1-olAcetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

Useful:

• Canonical SMILES: CCCCC=CCCCCOC(=O)C
• Isomeric SMILES: CCCC/C=C/CCCCOC(=O)C
• Uses: (E)-5-Decen-1-ol Acetate is an insect sex-attractant pheromone component and is a major component in the Peach Twig Borer pheromone.

Technology Process of (E)-5-Decen-1-yl acetate

There total 36 articles about (E)-5-Decen-1-yl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

(E)-5-decen-1-ol (56578-18-8) + acetic anhydride (108-24-7) → (E)-5-decen-1-yl acetate (38421-90-8)

Guidance literature:

With dmap; at 100 ℃; for 2h;

DOI:10.1007/BF01157355

Reference yield: 75.0%

1-acetoxy-5-decene (133074-61-0) → (E)-5-decen-1-yl acetate (38421-90-8)

Guidance literature:

With ethene; Mo(N^iPrPh)-(CHCMe₂Ph)(Me₂Pyrr)(OBitet); at 22 ℃; for 0.25h; under 3040.2 Torr; stereoselective reaction; Inert atmosphere;

DOI:10.1021/ja205002v

Reference yield:

(E)-5-decene (7433-56-9) + 5-hexenyl acetate (5048-26-0) → (E)-5-decen-1-yl acetate (38421-90-8)

Guidance literature:

upstream raw materials:

(Z)-dec-5-en-1-ol

acetic anhydride

(E)-5-decen-1-ol

acetyl chloride

Downstream raw materials:

(E)-5-decen-1-ol

Refernces

• 1、 -. "Synthesizing method for 5E-decene-1-alcohol and acetic acid 5E-decenoate". Paragraph 0090; 0091; 0092; 0094. . Retrieved 2017/04/03.
• 2、 -. "Production of pheromones and fragrances from substituted and unsubstituted 1-alken-3yl alkylates". Page/Page column 5. . Retrieved 2010/05/13.