Ethanone, 1-(2-benzoylcyclopropyl)-, cis-

Base Information

Chemical Name:Ethanone, 1-(2-benzoylcyclopropyl)-, cis-
CAS No.:64390-03-0
Molecular Formula:C₁₂H₁₂O₂
Molecular Weight:188.226
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ethanone, 1-(2-benzoylcyclopropyl)-, cis-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Ethanone, 1-(2-benzoylcyclopropyl)-, cis-

There total 10 articles about Ethanone, 1-(2-benzoylcyclopropyl)-, cis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: C₁₂H₁₁NO₃

: 78-94-4,25038-87-3
methyl vinyl ketone

: 1-((1S,2S)-2-benzoylcyclopropyl)ethanone

: 35553-87-8,64390-03-0,64390-04-1
cis-1-Acetyl-2-benzoylcyclopropan

Guidance literature:: With C₂₂H₃₁O₂Rh; cesium acetate; dibenzoyl peroxide; In 2,2,2-trifluoroethanol; at 23 ℃; for 16h; stereoselective reaction;
DOI:10.1039/c8sc05702h

Reference yield:

: C₁₆H₉Cl₂NO₃

: 78-94-4,25038-87-3
methyl vinyl ketone

: 64390-03-0
cis-1-Acetyl-2-benzoylcyclopropan

: 64390-04-1
trans 1-(2-benzoylcyclopropyl)ethanone

Guidance literature:: With C₂₄H₃₄Cl₄Rh₂; sodium acetate; In 2,2,2-trifluoroethanol; at 23 ℃; for 20h; Overall yield = 75 %; Overall yield = 14.1 mg; diastereoselective reaction;
DOI:10.1021/jacs.8b04243

Reference yield:

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 64390-03-0
cis-1-Acetyl-2-benzoylcyclopropan

: 64390-04-1
trans 1-(2-benzoylcyclopropyl)ethanone

Guidance literature:: Multi-step reaction with 6 steps

1.1: acetic acid; lithium bromide; sodium periodate / 20 °C

2.1: potassium carbonate / methanol; tetrahydrofuran / 3 h / 20 °C

3.1: tert.-butyl lithium / diethyl ether; hexane / 0.5 h / -78 °C

3.2: -78 °C

4.1: hydrogenchloride / water / 2 h / 20 °C

5.1: copper diacetate; sodium sulfate; pyridine; oxygen / 1,2-dichloro-ethane / 48 h / 20 °C

6.1: cesium acetate; C₁₆H₂₂Cl₄Rh₂ / 2,2,2-trifluoroethanol / 16 h / 21 °C

With pyridine; hydrogenchloride; sodium periodate; C₁₆H₂₂Cl₄Rh₂; tert.-butyl lithium; oxygen; cesium acetate; copper diacetate; potassium carbonate; acetic acid; sodium sulfate; lithium bromide; In tetrahydrofuran; methanol; diethyl ether; hexane; 2,2,2-trifluoroethanol; water; 1,2-dichloro-ethane;
DOI:10.1021/ja506579t