Methyl 3-(4-methoxyphenoxy)benzoate

Base Information

Chemical Name:Methyl 3-(4-methoxyphenoxy)benzoate
CAS No.:64691-60-7
Molecular Formula:C15H14O4
Molecular Weight:258.26900
Hs Code.:
ChEMBL ID:CHEMBL250473
DSSTox Substance ID:DTXSID60408523
Nikkaji Number:J372.546D

Synonyms:Methyl 3-(4-methoxyphenoxy)benzoate;64691-60-7;CHEMBL250473;DTXSID60408523;AKOS002685392

Suppliers and Price of Methyl 3-(4-methoxyphenoxy)benzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl3-(4-Methoxyphenoxy)benzoate
10g
$ 1385.00

TRC
Methyl3-(4-Methoxyphenoxy)benzoate
5g
$ 815.00

TRC
Methyl3-(4-Methoxyphenoxy)benzoate
1g
$ 175.00

Total 0 raw suppliers

Chemical Property of Methyl 3-(4-methoxyphenoxy)benzoate

Chemical Property:

Boiling Point:372.6±27.0 °C(Predicted)
PSA：44.76000
Density:1.163±0.06 g/cm3(Predicted)
LogP:3.27410
XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:258.08920892
Heavy Atom Count:19
Complexity:284

Purity/Quality:: Methyl3-(4-Methoxyphenoxy)benzoate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC1=CC=C(C=C1)OC2=CC=CC(=C2)C(=O)OC
Uses Methyl 3-(4-Methoxyphenoxy)benzoate is an intermediate in the synthesis of 3-(4''-Hydroxy)phenoxybenzoic Acid (H951225), which is a metabolite of pyrethroid insecticides such as: Deltamethrin, Permethrin, Cypermethrin, Fenvalerate, Decamethrin.

Technology Process of Methyl 3-(4-methoxyphenoxy)benzoate

There total 5 articles about Methyl 3-(4-methoxyphenoxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

: 618-89-3
methyl 3-bromobenzoate

: 150-76-5
4-methoxy-phenol

: 64691-60-7
methyl 3-(4-methoxyphenoxy)benzoate

Guidance literature:: With sodium hydride; copper(l) chloride; In N,N-dimethyl-formamide; at 160 ℃; for 6h;
DOI:10.1016/j.tet.2007.07.078

Reference yield:

: 19438-10-9
methyl 3-hydroxybenzoate

: 5720-07-0
4-methoxyphenylboronic acid

: 64691-60-7
methyl 3-(4-methoxyphenoxy)benzoate

Guidance literature:: With copper diacetate; triethylamine; In dichloromethane; at 20 ℃;
DOI:10.1016/j.bmcl.2006.12.048

Reference yield:

: 123-31-9,8027-02-9
hydroquinone

: 64691-60-7
methyl 3-(4-methoxyphenoxy)benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 32 percent / aq. NaOH / 0.5 h / Heating

2: 25 percent / NaH; CuCl / dimethylformamide / 6 h / 160 °C

With sodium hydroxide; sodium hydride; copper(l) chloride; In N,N-dimethyl-formamide; 2: Ullmann diaryl ether synthesis;
DOI:10.1016/j.tet.2007.07.078