Phenazine, 2-(1,1-dimethylethyl)-

Base Information

• Chemical Name: Phenazine, 2-(1,1-dimethylethyl)-
• CAS No.: 6479-87-4
• Molecular Formula: C₁₆H₁₆N₂
• Molecular Weight: 236.316
• Mol file: 6479-87-4.mol

Synonyms:

Chemical Property of Phenazine, 2-(1,1-dimethylethyl)-

Chemical Property:

• PSA: 25.78000
• LogP: 4.08050

Purity/Quality:

95% ^*data from raw suppliers

2-tert-Butylphenazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenazine, 2-(1,1-dimethylethyl)-

There total 9 articles about Phenazine, 2-(1,1-dimethylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Nitrosobenzene (586-96-9) + 4,4′-di(tert-butyl)azobenzene (7775-81-7) → 2-(tert-butyl)phenazine (6479-87-4)

Guidance literature:

With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; zinc trifluoromethanesulfonate; acetic acid; In 1,2-dichloro-ethane; at 140 ℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/acs.orglett.9b00502

Reference yield: 62.0%

C11H15NO2 + Nitrosobenzene (586-96-9) → 2-(tert-butyl)phenazine (6479-87-4)

Guidance literature:

With silver hexafluoroantimonate; acetic acid; silver carbonate; In 2,2,2-trifluoroethanol; at 140 ℃; for 16h; Schlenk technique;

DOI:10.1016/j.tetlet.2021.153550

Reference yield: 62.0%

→ 2-(tert-butyl)phenazine (6479-87-4)

Guidance literature:

With silver hexafluoroantimonate; acetic acid; silver carbonate; In 2,2,2-trifluoroethanol; at 140 ℃; for 16h; Schlenk technique; Sealed tube;

upstream raw materials:

4-t-butyl-1,2-benzoquinone

1,2-diamino-benzene

Nitrosobenzene

4,4′-di(tert-butyl)azobenzene