4-(Bromomethyl)-2-isopropyl-1-methoxybenzene

Base Information Edit

Chemical Name:4-(Bromomethyl)-2-isopropyl-1-methoxybenzene
CAS No.:64929-62-0
Molecular Formula:C11H15BrO
Molecular Weight:243.143
Hs Code.:
DSSTox Substance ID:DTXSID00564470
Wikidata:Q82449166
Mol file:64929-62-0.mol

Synonyms:64929-62-0;4-(bromomethyl)-2-isopropyl-1-methoxybenzene;SCHEMBL6690387;DTXSID00564470;GS2784;4-(Bromomethyl)-1-methoxy-2-(propan-2-yl)benzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-(Bromomethyl)-2-isopropyl-1-methoxybenzene Edit

Chemical Property:

XLogP3:3.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:242.03063
Heavy Atom Count:13
Complexity:147

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)C1=C(C=CC(=C1)CBr)OC

Technology Process of 4-(Bromomethyl)-2-isopropyl-1-methoxybenzene

There total 10 articles about 4-(Bromomethyl)-2-isopropyl-1-methoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 31816-29-2
4-Methoxy-3-isopropylbenzyl alcohol

: 64929-62-0
3-isopropyl-4-methoxybenzyl bromide

Guidance literature:: With pyridine; phosphorus tribromide; In benzene; for 3h; Ambient temperature;
DOI:10.1080/00397919108020799

Reference yield:

: 134435-48-6
3-(1-methylethenyl)-4-methoxyphenylethyl acetate

: 64929-62-0
3-isopropyl-4-methoxybenzyl bromide

Guidance literature:: Multi-step reaction with 7 steps

1: 99 percent / H₂ / Pd/C / diethyl ether / 2068.6 Torr

2: 75 percent / PCC, HOAc, Celite, molecular sieve 4A / CH₂Cl₂

4: 84 percent / KBr, m-CPBA, 18-cr-6 / CH₂Cl₂ / 0.5 h / 0 °C

5: 98 percent / Mg / tetrahydrofuran

6: 97 percent / NaBH₄ / methanol / 0.2 h / Ambient temperature

7: 98 percent / PBr₃, pyridine / benzene / 3 h / Ambient temperature

With pyridine; sodium tetrahydroborate; 18-crown-6 ether; 4 A molecular sieve; Celite; hydrogen; phosphorus tribromide; magnesium; acetic acid; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; potassium bromide; palladium on activated charcoal; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; benzene;
DOI:10.1080/00397919108020799

Reference yield:

: 2944-47-0
o-isopropylanisole

: 64929-62-0
3-isopropyl-4-methoxybenzyl bromide

Guidance literature:: Multi-step reaction with 4 steps

1: 84 percent / KBr, 18-crown-6, m-CPBA / CH₂Cl₂ / 0.5 h / 0 °C

2: 1) Mg / 1) THF, 2) cooling, then reflux, 5 min

3: 97 percent / NaBH₄ / methanol / 0.2 h / 0 °C

4: 98 percent / PBr₃, pyridine / benzene / 3 h

With pyridine; sodium tetrahydroborate; 18-crown-6 ether; phosphorus tribromide; magnesium; 3-chloro-benzenecarboperoxoic acid; potassium bromide; In methanol; dichloromethane; benzene;