Dibenzyl Bromomalonate

Base Information

Chemical Name:Dibenzyl Bromomalonate
CAS No.:65100-24-5
Molecular Formula:C17H15BrO4
Molecular Weight:363.208
Hs Code.:
DSSTox Substance ID:DTXSID20569644
Nikkaji Number:J2.510.366A
Wikidata:Q82456830

Synonyms:Dibenzyl Bromomalonate;65100-24-5;Dibenzyl bromopropanedioate;SCHEMBL3206832;DTXSID20569644;UIEAFXRIPQUIBW-UHFFFAOYSA-N;2-bromo-malonic acid dibenzyl ester

Suppliers and Price of Dibenzyl Bromomalonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Dibenzyl Bromomalonate

Chemical Property:

XLogP3:4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:8
Exact Mass:362.01537
Heavy Atom Count:22
Complexity:326

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)COC(=O)C(C(=O)OCC2=CC=CC=C2)Br

Technology Process of Dibenzyl Bromomalonate

There total 4 articles about Dibenzyl Bromomalonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 15014-25-2
malonic acid dibenzyl ester

: 65100-24-5
dibenzyl 2-bromomalonate

Guidance literature:: malonic acid dibenzyl ester; With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 0 ℃; for 0.5h;

With carbon tetrabromide; In tetrahydrofuran; at -78 ℃; for 6h;
DOI:10.1002/chem.201800046

Reference yield:

: 100-39-0
benzyl bromide

: 65100-24-5
dibenzyl 2-bromomalonate

Guidance literature:: Multi-step reaction with 2 steps

1: NEt₃ / dimethylformamide / 20 °C

2: Br₂ / CHCl₃ / Irradiation

With bromine; triethylamine; In chloroform; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)81982-6

Reference yield:

: 100-51-6,185532-71-2
benzyl alcohol

: 65100-24-5
dibenzyl 2-bromomalonate

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / concentrated sulfuric acid / toluene / 2 h / Heating

2: 28 percent / bromine / CCl₄ / 2 h / Irradiation

With sulfuric acid; bromine; In tetrachloromethane; toluene;
DOI:10.1139/v01-100