Bis(4-nitrophenyl)methane

Base Information

• Chemical Name: Bis(4-nitrophenyl)methane
• CAS No.: 1817-74-9
• Molecular Formula: C13H10 N2 O4
• Molecular Weight: 258.233
• Hs Code.: 29042090
• European Community (EC) Number: 217-330-8
• NSC Number: 631621,6337
• DSSTox Substance ID: DTXSID1061992
• Nikkaji Number: J111.359C
• Wikidata: Q81989782
• ChEMBL ID: CHEMBL1880969
• Mol file: 1817-74-9.mol

Synonyms:4,4'-Dinitrodiphenylmethane;1817-74-9;Bis(4-nitrophenyl)methane;Benzene, 1,1'-methylenebis[4-nitro-;Methane, bis(p-nitrophenyl)-;1-nitro-4-[(4-nitrophenyl)methyl]benzene;BIS(P-NITROPHENYL)METHANE;4,4-DINITRODIPHENYLMETHANE;MLS002637880;NSC 6337;EINECS 217-330-8;1,1'-methanediylbis(4-nitrobenzene);4,4/'-DINITRODIPHENYLMETHANE;NSC631621;Benzene, 1,1'-methylenebis(4-nitro-;AI3-03273;NSC6337;4,4'-DINITROPHENYLMETHANE;p,p'-Dinitrodiphenylmethan;Bis-(p-nitrophenyl)-methane;Oprea1_157572;SCHEMBL44366;CHEMBL1880969;DTXSID1061992;Benzene,1'-methylenebis[4-nitro-;HMS3093E04;NSC-6337;BBL004036;MFCD00059184;STK396590;1-Nitro-4-(4-nitrobenzyl)benzene #;AKOS003245347;Benzene, 1,1'-methylenebis*4-nitro-;NSC-631621;AS-62219;SMR001547392;CS-0157624;D0833;FT-0696307;T70458;Hydroxy(4-(4-(hydroxy(oxido)amino)benzyl)phenyl)azane oxide

Chemical Property of Bis(4-nitrophenyl)methane

Chemical Property:

• Vapor Pressure: 1.06E-07mmHg at 25°C
• Melting Point: 185 °C
• Boiling Point: 445.1°Cat760mmHg
• Flash Point: 221°C
• PSA: 91.64000
• Density: 1.341g/cm³
• LogP: 4.14020
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 258.06405680
• Heavy Atom Count: 19
• Complexity: 289

Purity/Quality:

98%,99%, ^*data from raw suppliers

4,4'-Dinitrodiphenylmethane >99.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1CC2=CC=C(C=C2)[N+](=O)[O-])[N+](=O)[O-]

Technology Process of Bis(4-nitrophenyl)methane

There total 22 articles about Bis(4-nitrophenyl)methane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

4,4'-dinitrobenzophenone (1033-26-7) → bis(4-nitrophenyl)methane (1817-74-9)

Guidance literature:

With zinc dibromide; triethyl phosphite; at 20 ℃; for 8h; Inert atmosphere;

DOI:10.1002/ejoc.201500332

Reference yield: 34.0%

Diphenylmethane (101-81-5) → bis(4-nitrophenyl)methane (1817-74-9)

Guidance literature:

With sulfuric acid; nitric acid; acetic acid; at 5 - 10 ℃; for 2h;

Reference yield: 31.0%

4,4'-diamino diphenyl methane (101-77-9) → bis(4-nitrophenyl)methane (1817-74-9)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 40h; Heating;

upstream raw materials:

methanol

3-chloro-1,1-bis-(4-nitro-phenyl)-acetone

sodium methylate

4-benzyl-1-nitrobenzene

Downstream raw materials:

4-(4-nitrophenyl)methylaniline

2,2-bis(4-nitrophenyl)ethanoic acid

2,2',4,4'-tetranitrodiphenylmethane

4,4'-dinitrodiphenylmethyl anion

Refernces

• 1、 Jarczewski,Leffek. "". . p. 24. Retrieved 1972.
• 2、 McLean, Euan B.,Gauchot, Vincent,Brunen, Sebastian,Burns, David J.,Lee, Ai-Lan. "Dual copper- and photoredox-catalysed C(sp2)-C(sp3) coupling". supporting information. p. 4238 - 4241. Retrieved 2019/04/30.
• 3、 Singh, Manish K.,Lakshman, Mahesh K.. "Diarylmethanes through an Unprecedented Palladium-Catalyzed C-C Cross-Coupling of 1-(Aryl)methoxy-1 H-Benzotriazoles with Arylboronic Acids". . p. 4156 - 4162. Retrieved 2016/01/09.