Methyl pentafluoromethacrylate

Base Information

• Chemical Name: Methyl pentafluoromethacrylate
• CAS No.: 685-09-6
• Molecular Formula: C5H3 F5 O2
• Molecular Weight: 190.07
• Hs Code.: 2916200090
• European Community (EC) Number: 671-797-6
• DSSTox Substance ID: DTXSID40218622
• Nikkaji Number: J26.247A
• Mol file: 685-09-6.mol

Synonyms:Methyl pentafluoromethacrylate;685-09-6;Methyl perfluoromethacrylate;methyl 3,3-difluoro-2-(trifluoromethyl)prop-2-enoate;methylpentafluoromethacrylate;Pentafluoromethacrylic acid methyl ester;Methacrylic acid, pentafluoro-, methyl ester;BRN 1566924;ACRYLIC ACID, 3,3-DIFLUORO-2-(TRIFLUOROMETHYL)-, METHYL ESTER;Methylester kyseliny pentafluormethakrylove [Czech];MFCD00153210;Methylester kyseliny pentafluormethakrylove;2-Propenoic acid, 3,3-difluoro-2-(trifluoromethyl)-, methyl ester;methyl 3,3-difluoro-2-(trifluoromethyl)acrylate;SCHEMBL2957666;DTXSID40218622;AKOS006229572;BS-24486;CS-0206441;FT-0628774;A836167;methyl 3,3-bis(fluoranyl)-2-(trifluoromethyl)prop-2-enoate;3,3-difluoro-2-(trifluoromethyl)-2-propenoic acid methyl ester

Chemical Property of Methyl pentafluoromethacrylate

Chemical Property:

• Vapor Pressure: 35mmHg at 25°C
• Boiling Point: 94 °C
• Flash Point: 21.6°C
• PSA: 26.30000
• Density: 1.407g/cm³
• LogP: 1.87230
• Storage Temp.: Keep Cold
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 2
• Exact Mass: 190.00532014
• Heavy Atom Count: 12
• Complexity: 212

Purity/Quality:

99% ^*data from raw suppliers

Methyl pentafluoromethacrylate 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xi
• Hazard Codes: F,Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)C(=C(F)F)C(F)(F)F

Technology Process of Methyl pentafluoromethacrylate

There total 4 articles about Methyl pentafluoromethacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

methyl 2-(trifluoromethyl)-3,3,3-trifluoropropionate (360-54-3) → methyl perfluoromethacrylate (685-09-6)

Guidance literature:

With triethylamine boron trifluoride; for 3h; Heating;

DOI:10.1021/ma021131i

Reference yield:

methyl α,β-dichloropentafluoroisobutyrate (1480-83-7) → methyl perfluoromethacrylate (685-09-6)

Guidance literature:

With zinc; In diethyl ether;

DOI:10.1007/BF00844089

Reference yield:

3,3,3-trifluoro-1,1-dimethoxy-2-trifluoromethyl-propene (37587-69-2) → methyl perfluoromethacrylate (685-09-6)

Guidance literature:

With boron trifluoride diethyl etherate;

DOI:10.1016/0040-4020(73)85001-X

upstream raw materials:

methyl α,β-dichloropentafluoroisobutyrate

3,3,3-trifluoro-1,1-dimethoxy-2-trifluoromethyl-propene

methyl 2-(trifluoromethyl)-3,3,3-trifluoropropionate

Downstream raw materials:

methyl 2-fluoroformyl-2-trifluoromethyl-3-phenyl-4-pentenoate

trimethylsilyl fluoride

(E)-3-Fluoro-2-trifluoromethyl-3-(trimethylsilanyl-amino)-acrylic acid methyl ester

(E)-3-Dimethylamino-3-fluoro-2-trifluoromethyl-acrylic acid methyl ester

Refernces