Benzenebutanoic acid, 3-methyl-, methyl ester

Base Information

• Chemical Name: Benzenebutanoic acid, 3-methyl-, methyl ester
• CAS No.: 65462-68-2
• Molecular Formula: C12H16O2
• Molecular Weight: 192.25400
• Mol file: 65462-68-2.mol

Synonyms:

Chemical Property of Benzenebutanoic acid, 3-methyl-, methyl ester

Chemical Property:

• PSA: 26.30000
• LogP: 2.49070

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenebutanoic acid, 3-methyl-, methyl ester

There total 2 articles about Benzenebutanoic acid, 3-methyl-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

3-methylstyrene (100-80-1) + Methyl thioglycolate (2365-48-2) → methyl 4-(m-tolyl)butanoate (65462-68-2)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); triethyl phosphite; In 1,2-dichloro-ethane; at 80 ℃; for 12h; under 760.051 Torr; Inert atmosphere; Schlenk technique;

DOI:10.1039/c9cc05378f

Reference yield:

acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) + m-xylene (108-38-3,104809-90-7) → methyl 4-(m-tolyl)butanoate (65462-68-2)

Guidance literature:

With di-tert-butyl peroxide; iodine;

DOI:10.1007/BF00923656

upstream raw materials:

acrylic acid methyl ester

m-xylene

3-methylstyrene

Methyl thioglycolate

Refernces