(NZ)-N-[(4-phenylphenyl)methylidene]hydroxylamine

Base Information

Chemical Name:(NZ)-N-[(4-phenylphenyl)methylidene]hydroxylamine
CAS No.:40143-27-9
Molecular Formula:C13H11 N O
Molecular Weight:197.236
Hs Code.:2928000090
NSC Number:93959
Nikkaji Number:J1.113.931K
Mol file:40143-27-9.mol

Synonyms:(NZ)-N-[(4-phenylphenyl)methylidene]hydroxylamine;40143-27-9;NSC93959;4-Biphenylaldehydeoxime;Biphenyl-4-carbaldehydeoxime;SCHEMBL4686720;(E)-biphenyl-4-carbaldehyde oxime;NSC-93959;1089301-82-5

Suppliers and Price of (NZ)-N-[(4-phenylphenyl)methylidene]hydroxylamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-Phenylbenzaldoxime
2.5g
$ 85.00

Sigma-Aldrich
4-Phenylbenzaldoxime analytical standard
1g
$ 45.50

Crysdot
[1,1'-Biphenyl]-4-carbaldehydeoxime 97%
5g
$ 805.00

AHH
4-Biphenylaldehydeoxime 96%
50g
$ 310.00

Total 12 raw suppliers

Chemical Property of (NZ)-N-[(4-phenylphenyl)methylidene]hydroxylamine

Chemical Property:

Vapor Pressure:4.92E-05mmHg at 25°C
Boiling Point:334.8°Cat760mmHg
Flash Point:206.9°C
PSA：32.59000
Density:1.05g/cm³
LogP:3.16170
XLogP3:3.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:197.084063974
Heavy Atom Count:15
Complexity:201

Purity/Quality:

97% ^*data from raw suppliers

4-Phenylbenzaldoxime ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:C1=CC=C(C=C1)C2=CC=C(C=C2)C=NO
Isomeric SMILES:C1=CC=C(C=C1)C2=CC=C(C=C2)/C=N\O
Uses 4-Phenylbenzaldoxime is a reactant in the design and synthesis of substituted-isoxazole derivatives as farnesoid X receptor (FXR) antagonists.

Technology Process of (NZ)-N-[(4-phenylphenyl)methylidene]hydroxylamine

There total 4 articles about (NZ)-N-[(4-phenylphenyl)methylidene]hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 3218-36-8
4-Phenylbenzaldehyde

: 40143-27-9
biphenyl-4-carbaldehyde oxime

Guidance literature:: With hydroxylamine hydrochloride; sodium carbonate; In methanol; water; at 20 ℃; for 3h;
DOI:10.1039/c6ra02222g

Reference yield:

: 92-66-0
4-bromo-1,1'-biphenyl

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 40143-27-9
biphenyl-4-carbaldehyde oxime

Guidance literature:: 4-bromo-1,1'-biphenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -50 ℃; for 0.5h; Inert atmosphere;

N,N-dimethyl-formamide; In tetrahydrofuran; hexane; at -50 - 20 ℃; for 1h; Inert atmosphere;

With hydroxylamine hydrochloride; potassium carbonate; In tetrahydrofuran; hexane; at 20 ℃; for 2h; Inert atmosphere;
DOI:10.1016/j.tet.2018.06.044

Reference yield:

: 3597-91-9
biphenyl-4-yl methanol

: 40143-27-9
biphenyl-4-carbaldehyde oxime

Guidance literature:: Multi-step reaction with 2 steps

1: pyridinium chlorochromate; magnesium sulfate / chloroform / 3 h / Sealed tube

2: hydroxylamine hydrochloride; sodium acetate / water; ethanol; tetrahydrofuran / 72 h / 20 °C

With hydroxylamine hydrochloride; sodium acetate; magnesium sulfate; pyridinium chlorochromate; In tetrahydrofuran; ethanol; chloroform; water;
DOI:10.1016/j.tetlet.2015.12.038