9,12-Tetradecadien-1-ol, acetate, (Z,E)-

Base Information

• Chemical Name: 9,12-Tetradecadien-1-ol, acetate, (Z,E)-
• CAS No.: 31654-77-0
• Molecular Formula: C16H28 O2
• Molecular Weight: 252.397
• Hs Code.: 2915390090
• European Community (EC) Number: 250-753-6,608-490-3
• DSSTox Substance ID: DTXSID80860462
• Mol file: 31654-77-0.mol

Synonyms:cis-9-trans-12-tetradecadien-1-ol acetate;cis-9-trans-12-tetradecadien-1-ol acetate, (E,Z)-isomer

Chemical Property of 9,12-Tetradecadien-1-ol, acetate, (Z,E)-

Chemical Property:

• Vapor Pressure: 0.000125mmHg at 25°C
• Boiling Point: 334.8°Cat760mmHg
• Flash Point: 102.3°C
• PSA: 26.30000
• Density: 0.89g/cm³
• LogP: 4.80260
• Storage Temp.: −20°C
• Solubility.: Benzene (Slightly), Chloroform (Slightly), Methanol (Slightly)
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 252.208930132
• Heavy Atom Count: 18
• Complexity: 242

Purity/Quality:

98% or more ^*data from raw suppliers

CIS-9,TRANS-12-TETRADECADIENYL ACETATE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC=CCC=CCCCCCCCCOC(=O)C
• Uses: (9Z,12E)-Tetradecadien-1-yl Acetate is a sex pheromone component?of Noctuidae in Antilles.

Technology Process of 9,12-Tetradecadien-1-ol, acetate, (Z,E)-

There total 2 articles about 9,12-Tetradecadien-1-ol, acetate, (Z,E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

(Z,E)-9,12-tetradecadien-1-ol (70654-44-3,51937-00-9) + acetic anhydride (108-24-7) → Tetradec-9Z,12E-dien-1-yl Acetate (30507-70-1) + (9E,12E)-tetradeca-9,12-dien-1-yl acetate (70654-47-6) + (Z,Z)-9,12-tetradecadienyl acetate (51354-22-4) + (9E,12Z)-9,12-tetradecadienyl acetate (31654-77-0)

Guidance literature:

In pyridine;

Reference yield:

9-acetoxynonal (29541-97-7) + Triphenyl-((E)-1-trimethylsilanyl-pent-3-enyl)-phosphonium; bromide (98291-64-6,98291-65-7) → (9E,12E)-tetradeca-9,12-dien-1-yl acetate (70654-47-6) + Acetic acid (9Z,12E)-tetradeca-9,12-dienyl ester (30507-70-1,31654-77-0,51354-22-4,68887-73-0,70654-47-6)

Guidance literature:

With cesium fluoride; In N,N-dimethyl-formamide; Yield given. Yields of byproduct given; Ambient temperature;

DOI:10.1016/S0040-4039(00)94907-4

upstream raw materials:

9-acetoxynonal

Triphenyl-((E)-1-trimethylsilanyl-pent-3-enyl)-phosphonium; bromide

(Z,E)-9,12-tetradecadien-1-ol

acetic anhydride

Refernces

• 1、 Bestmann, Hans Juergen,Koschatzky, Karl-Heinrich,Plenchette, Alain,Suess, Joachim,Vostrowsky, Otto. "Pheromones, XXXV. - Stereoselective Syntheses of 1,4-Alkadienes". . p. 536 - 544. Retrieved 2007/10/02.