Cinnamyl 2-methylbutyrate

Base Information

Chemical Name:Cinnamyl 2-methylbutyrate
CAS No.:67883-77-6
Molecular Formula:C14H18O2
Molecular Weight:218.296
Hs Code.:
European Community (EC) Number:267-552-4
Nikkaji Number:J2.536.017F,J287.624H
Mol file:67883-77-6.mol

Synonyms:Cinnamyl 2-methylbutyrate;3-Phenylallyl 2-methylbutyrate;EINECS 267-552-4;67883-77-6;Butanoic acid, 2-methyl-, 3-phenyl-2-propenyl ester;Butanoic acid, 2-methyl-, 3-phenyl-2-propen-1-yl ester;2-Methylbutanoic acid 3-phenyl-2-propenyl ester;2-Methylbutanoic acid (E)-3-phenyl-2-propenyl ester

Suppliers and Price of Cinnamyl 2-methylbutyrate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Cinnamyl 2-methylbutyrate

Chemical Property:

Vapor Pressure:0.000269mmHg at 25°C
Boiling Point:323°Cat760mmHg
Flash Point:128.3°C
Density:1.006g/cm³
XLogP3:3.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:218.130679813
Heavy Atom Count:16
Complexity:227

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCC(C)C(=O)OCC=CC1=CC=CC=C1
Isomeric SMILES:CCC(C)C(=O)OC/C=C/C1=CC=CC=C1

Technology Process of Cinnamyl 2-methylbutyrate

There total 4 articles about Cinnamyl 2-methylbutyrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 5856-79-1,57526-28-0
iso-butyl chloroformate

: 104-54-1
3-Phenylpropenol

: 67883-77-6
cinnamyl 2-methylbutyrate

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃; Reflux;
DOI:10.1002/cbdv.200800310

Reference yield: 77.0%

: cinnamyl 2-bromo-2-methylbutanoate

: 67883-77-6
cinnamyl 2-methylbutyrate

: 1310051-09-2
2-ethyl-2-methyl-3-phenylpent-4-enoic acid

Guidance literature:: cinnamyl 2-bromo-2-methylbutanoate; With tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; indium(III) chloride; indium; chloro-trimethyl-silane; triethylamine; at 10 - 30 ℃; Inert atmosphere; Sonication;

With water; ammonium chloride; In tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; optical yield given as %de; diastereoselective reaction; Saturated solution;
DOI:10.1016/j.tet.2011.03.079

Reference yield:

: 116-53-0,600-07-7
2-Methylbutanoic acid

: 67883-77-6
cinnamyl 2-methylbutyrate

: 1310051-09-2
2-ethyl-2-methyl-3-phenylpent-4-enoic acid

Guidance literature:: Multi-step reaction with 3 steps

1.1: N-Bromosuccinimide / Inert atmosphere; Heating

2.1: Inert atmosphere

3.1: tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; indium(III) chloride; indium; chloro-trimethyl-silane; triethylamine / 10 - 30 °C / Inert atmosphere; Sonication

3.2: Saturated solution

With tetrahydrofuran; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; indium(III) chloride; indium; N-Bromosuccinimide; chloro-trimethyl-silane; triethylamine;
DOI:10.1016/j.tet.2011.03.079