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Cinnamyl alcohol Manufacturer/High quality/Best price/In stock Manufacturer/High quality/Best price/In stock
Cas No: 104-54-1
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
High quality Cinnamyl Alcohol
Cas No: 104-54-1
USD $ 6.0-7.0 / Kilogram 1 Kilogram 2000 Metric Ton/Year Xiamen BaiFuchem Co.,Ltd Contact Supplier
High purity Various Specifications Cinnamyl alcohol CAS:104-54-1
Cas No: 104-54-1
USD $ 100.0-500.0 / Gram 1 Gram 99999 Gram/Year Hangzhou Dingyan Chem Co., Ltd Contact Supplier
High quality Cinnamyl Alcohol supplier in China
Cas No: 104-54-1
No Data 1 Kilogram 30 Metric Ton/Month Simagchem Corporation Contact Supplier
99.5% Cinnamyl alcohol cas 104-54-1
Cas No: 104-54-1
No Data 200 Kilogram 2000 Metric Ton/Year Hefei TNJ chemical industry co.,ltd Contact Supplier
Cinnamyl alcohol, Cinnamic alcohol, CAS: 104-54-1, Methyl cinnamate
Cas No: 104-54-1
No Data 1 Metric Ton Metric Ton/Day Nanjing Yuance Industry&Trade Co., Ltd. Contact Supplier
Cinnamyl alcohol
Cas No: 104-54-1
No Data 10 Milligram 1 Kilogram/Day shanghai Tauto Biotech Co., Ltd Contact Supplier
(E)-3-phenyl-2-propen-1-ol
Cas No: 104-54-1
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
Cinnamyl alcohol
Cas No: 104-54-1
No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Cinnamyl alcohol CAS:104-54-1
Cas No: 104-54-1
USD $ 1.0-2.0 / Metric Ton 5 Metric Ton 1000 Metric Ton/Year Henan Sinotech Import&Export Corporation Contact Supplier

104-54-1 Usage

Purification Methods

Crystallise the alcohol from diethyl ether/pentane. [Beilstein 6 I 281.]

Uses

Cinnamyl alcohol was used to study the alkylation of 2,4-di-tert-butylphenol by cinnamyl alcohol using aluminum-containing mesoporous ethane-silica catalyst. It was used to study gold nanoparticles supported on titanium dioxide catalysed oxidative coupling of alcohols and amines to form the corresponding imines.

Uses

In perfumery; as deodorant in 12.5% solution in glycerol.

Contact allergens

Cinnamyl alcohol occurs (in esterified form) in storax, Myroxylon pereirae, cinnamon leaves, and hyacinth oil. It is obtained by the alkaline hydrolysis of storax and prepared synthetically by reducing cinnamal diacetate with iron filings and acetic acid, and from cinnamaldehyde by Meerwein-Ponndorf reduction with aluminum isopropoxide. Cinnamic alcohol is contained in the “fragrance mix.” As a fragrance allergen, it has to be mentioned by name in cosmetics within the EU. Occupational cases of contact dermatitis were reported in perfume industry. Patch tests can be positive in food handlers.

Description

As an organic compound, Cinnamic alcohol has a very distinct sweet, spicy, hyacinth odour that is found in resins, balsams and cinnamon leaves. It is used commonly in the fragrance industry due to its distinctive odour, which can be applied as a deodorant, fragrance and additive in cosmetic products and in the formulation of bath products, body and hand products, such as soaps, toothpaste, deodorants, etc. Besides, it also finds application as a food additive in chewing gum, bakery products, candy and soft drinks. Naturally, Cinnamyl alcohol is occurrent only in small amount, thus its industrial demand is usually fulfilled by chemical synthesis starting from the reduction of cinnamaldehyde.
Cinnamyl alcohol has been found to have a sensitising effect on some particular people, thus it is also considered as a Standardized Chemical Allergen. The physiologic effect of cinnamyl alcohol is caused by the Increased Histamine Release and cell-mediated Immunity.

Chemical Properties

colourless solid

References

https://en.wikipedia.org/wiki/Cinnamyl_alcohol
http://www.huidziekten.nl/allergie/stoffen/cinnamic-alcohol.htm
https://www.ulprospector.com/en/na/Food/Detail/13286/411638/Cinnamic-Alcohol
http://www.cosmeticsinfo.org/ingredient/cinnamyl-alcohol-0
https://pubchem.ncbi.nlm.nih.gov/compound/cinnamyl_alcohol#section=Top
http://www.somaiya.com/products/chemicals-pipeline/cinnamic-alcohol-1

Definition

ChEBI: A primary alcohol comprising an allyl core with a hydroxy substituent at the 1-position and a phenyl substituent at the 3-position (geometry of the C2C bond unspecified).
InChI:InChI=1/C9H10O/c10-8-4-7-9-5-2-1-3-6-9/h1-7,10H,8H2/b7-4+

104-54-1 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (93066)  Cinnamylalcohol  analytical standard 104-54-1 93066-50MG 1,100.97CNY Detail
TCI America (C0362)  Cinnamyl Alcohol  >97.0%(GC) 104-54-1 500g 345.00CNY Detail
TCI America (C0362)  Cinnamyl Alcohol  >97.0%(GC) 104-54-1 25g 100.00CNY Detail

104-54-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name cinnamyl alcohol

1.2 Other means of identification

Product number -
Other names 3-Phenyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:104-54-1 SDS

104-54-1Synthetic route

3-phenyl-propenal
104-55-2

3-phenyl-propenal

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With diphenylsilane; cesium fluoride at 25℃; for 0.05h;100%
With C28H28Cl2N4Pd; hydrogen In methanol at 30 - 35℃; under 760.051 Torr; for 8h; chemoselective reaction;100%
With C8H15BN2OS2; scandium tris(trifluoromethanesulfonate) In dichloromethane at 20℃; Reagent/catalyst; Schlenk technique; Inert atmosphere;100%
3-phenyl-2-propenyl tetrahydro-2H-pyran-2-yl ether
99441-44-8, 80356-15-6

3-phenyl-2-propenyl tetrahydro-2H-pyran-2-yl ether

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
bis(trimethylsilyl)sulphate In methanol; 1,2-dichloro-ethane for 1h; Ambient temperature;100%
With methanol at 20℃; for 0.5h;98%
With lithium borohydride In methanol at 20℃; for 0.416667h;96%
trimethylsilyl cinnamyl ether
109283-53-6, 141427-94-3, 18042-41-6

trimethylsilyl cinnamyl ether

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With iodine In methanol microwave irradiation;100%
With bismuth(lll) trifluoromethanesulfonate In methanol at 20℃; for 0.0333333h;97%
With poly (ethylene glycol)-sulfonated sodium montmorillonite nanocomposite In methanol at 20℃; for 0.0833333h;96%
cinnamyl formate
104-65-4

cinnamyl formate

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With hydrogenchloride In acetone at 20℃; for 0.25h;100%
With ethanol; 1,3-bis(mesityl)imidazolium chloride In tetrahydrofuran at 45℃; for 1h;100%
1-(tert-butyldimethylsilyloxy)-3-phenyl-2-propene
71700-50-0

1-(tert-butyldimethylsilyloxy)-3-phenyl-2-propene

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With iodine In methanol microwave irradiation;100%
With hafnium tetrakis(trifluoromethanesulfonate) In methanol at 20℃; for 4h;96%
With bismuth(lll) trifluoromethanesulfonate In methanol at 20℃; for 0.333333h;90%
ethyl 3-phenyl-2-propenoate
103-36-6

ethyl 3-phenyl-2-propenoate

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
Stage #1: ethyl 3-phenyl-2-propenoate With C48H62ErN7O2Si2; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In toluene at 110℃; for 6h; Inert atmosphere;
Stage #2: With silica gel In methanol at 60℃; for 3h; Inert atmosphere;
99%
With bis(acetylacetonato)dioxidomolybdenum(VI); 1,1,3,3-Tetramethyldisiloxane; Triphenylphosphine oxide In toluene at 100℃; for 72h; Inert atmosphere; Sealed tube;82%
With potassium borohydride; lithium chloride for 0.0833333h; microwave irradiation;55 % Chromat.
cinnamyl acetate
103-54-8

cinnamyl acetate

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With methanol at 80℃; for 6h; Inert atmosphere; Schlenk technique;99%
With methanol; potassium permanganate at 25℃; chemoselective reaction;94%
With 2C33H37N*H2O7S2; water at 40℃; for 24h;93%
methyl cinnamate
103-26-4

methyl cinnamate

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
Stage #1: methyl cinnamate With diethylzinc; lithium chloride In tetrahydrofuran; hexane at 20℃; for 6h; Inert atmosphere;
Stage #2: With sodium hydroxide In tetrahydrofuran; hexane; water at 20℃; for 8h; Inert atmosphere; chemoselective reaction;
98%
With Li(1+)*C12H28AlO3(1-) In tetrahydrofuran; hexane for 0.5h; Ambient temperature;97%
With sodium tetrahydroborate; ethanol; cerium(III) chloride heptahydrate at 20℃; for 24h; chemospecific reaction;95%
1-Phenyl-2-propen-1-ol
4393-06-0

1-Phenyl-2-propen-1-ol

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With triphenylsilyl perrhenate In diethyl ether at 0℃; for 0.5h;98%
With silica-supported monomeric vanadium-oxo species In acetonitrile at 20℃; for 6h; Reagent/catalyst; Temperature; Inert atmosphere;95%
With salicylic acid In water; acetonitrile for 16h; Reflux;90%
C15H20O2
1146218-82-7

C15H20O2

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
Stage #1: C15H20O2 With 2,4,6-trimethyl-pyridine; triethylsilyl trifluoromethyl sulfonate In dichloromethane at 0℃; for 0.5h; Inert atmosphere;
Stage #2: With water In dichloromethane Inert atmosphere;
98%
(E)-3-phenylpropenal
14371-10-9

(E)-3-phenylpropenal

A

3-Phenyl-1-propanol
122-97-4

3-Phenyl-1-propanol

B

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With hydrogen; (1,5-cyclooctadiene)(methoxy)iridium(l) dimer; ethyl-diphenyl-phosphane In toluene at 100℃; under 22800 Torr; for 7h; Product distribution; other catalysts, times, solvent;A 1%
B 97%
With hydrogen; (1,5-cyclooctadiene)(methoxy)iridium(l) dimer In toluene at 100℃; under 22800 Torr; for 7h;A 1%
B 97%
With C48H43ClN2P2Ru; potassium carbonate; isopropyl alcohol In neat (no solvent) at 90℃; for 1h; Catalytic behavior; Reagent/catalyst; Concentration; Schlenk technique;A 7 %Spectr.
B 90 %Spectr.
(E)-3-phenylpropenal
14371-10-9

(E)-3-phenylpropenal

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With C48H43ClN2P2Ru; ammonium formate In water; toluene at 90℃; for 10h; Catalytic behavior; Schlenk technique;97%
With n-butyllithium In diethyl ether; hexane at -78 - 20℃; Inert atmosphere;89%
With hydrogen In acetonitrile at 90℃; under 22502.3 Torr; for 2h; Reagent/catalyst; Flow reactor;32.4%
cinnamyl chloride
2687-12-9

cinnamyl chloride

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With iron(III) sulfate; water In toluene at 110℃; for 1h; Ionic liquid;96%
iodobenzene
591-50-4

iodobenzene

allyl alcohol
107-18-6

allyl alcohol

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With Pd(0) nanoparticles immobilized in TpPa-1 at 105℃; for 6h; Catalytic behavior; Heck Reaction;95%
With potassium carbonate In water at 100℃; for 12h; Catalytic behavior; Temperature; Time; Heck Reaction; Green chemistry;30 %Chromat.
methanol
67-56-1

methanol

Cinnamic acid
621-82-9

Cinnamic acid

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With tert.-butylhydroperoxide In water at 110℃; for 4h; Sealed tube;94%
Cinnamoyl chloride
102-92-1

Cinnamoyl chloride

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With poly-η-(pyridine)zinc borohydride In diethyl ether for 3.5h; Ambient temperature;93%
Cinnamic acid
621-82-9

Cinnamic acid

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
Stage #1: Cinnamic acid With 4-methyl-morpholine; 1,3,5-trichloro-2,4,6-triazine In 1,2-dimethoxyethane at 20℃; for 3h; Esterification;
Stage #2: With sodium tetrahydroborate In water at 0℃; Reduction;
93%
Stage #1: Cinnamic acid With sodium aminodiboranate In tetrahydrofuran at 20℃;
Stage #2: With water Solvent;
90%
With tributylphosphine; diphenylsilane; C45H25F12N7Ni2O9 In 1,4-dioxane at 100℃; for 16h;80%
2-(cinnamyloxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(cinnamyloxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With silica gel In ethyl acetate; Petroleum ether93%
In methanol at 20℃; for 5h; Inert atmosphere; Glovebox;86%
With silica gel at 25℃; Inert atmosphere; Glovebox;78%
C22H22OSi

C22H22OSi

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With Nonafluorobutanesulfonyl fluoride; TPGS-750-M In propan-1-ol; water at 50℃; for 8h; Reagent/catalyst; Solvent; Temperature; Green chemistry; chemoselective reaction;93%
3-phenyl-propenal
104-55-2

3-phenyl-propenal

A

3-Phenyl-1-propanol
122-97-4

3-Phenyl-1-propanol

B

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; antimony(III) chloride In tetrahydrofuran at 0℃; for 4h;A 7%
B 92%
With [Ru(2-(methylthio)-N-[(pyridin-2-yl)methyl]ethan-1-amine)(triphenylphosphine)Cl2]; potassium tert-butylate; hydrogen In isopropyl alcohol at 80℃; under 22502.3 Torr; for 16h; Reagent/catalyst; Inert atmosphere;A 5%
B 84%
With hydrogen In 1,4-dioxane at 180℃; under 7500.75 Torr; for 18h; Reagent/catalyst; Autoclave;A n/a
B 76%
3-Phenyl-2-propyn-1-ol
1504-58-1

3-Phenyl-2-propyn-1-ol

A

3-Phenyl-1-propanol
122-97-4

3-Phenyl-1-propanol

B

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With hydrogen; poly(amidoamine) dendron-stabilised Pd(0) nanoparticle In dichloromethane at 25℃; under 760.051 Torr; for 3h;A 8%
B 92%
With 1,1'-bis(diphenylphosphino)ferrocene; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; Butane-1,4-diol; potassium tert-butylate at 110℃; for 24h; Inert atmosphere;
C30H28O3

C30H28O3

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With cerium(III) chloride; sodium iodide In acetonitrile for 5h; ether cleavage; Heating;90%
diisopropyl-1H,1H,2H,2H-perfluorodecylsilyl cinnamyl ether
374928-86-6

diisopropyl-1H,1H,2H,2H-perfluorodecylsilyl cinnamyl ether

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With fluorosilicic acid In methanol; acetonitrile for 36h;90%
C16H16O2

C16H16O2

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone Product distribution / selectivity;90%
C12H16O2
1146218-83-8

C12H16O2

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
Stage #1: C12H16O2 With 2,4,6-trimethyl-pyridine; triethylsilyl trifluoromethyl sulfonate In dichloromethane at 0℃; for 0.5h; Inert atmosphere;
Stage #2: With water In dichloromethane Inert atmosphere; chemoselective reaction;
90%
trans (3-phenyloxiran-2-yl)methanol

trans (3-phenyloxiran-2-yl)methanol

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With carbon monoxide In water at 27℃; under 760.051 Torr; for 16h; chemoselective reaction;90%
Conditions
ConditionsYield
With carbon monoxide; water at 27℃; under 760.051 Torr; for 16h; chemoselective reaction;A 90%
B n/a
1-(4-methoxybenzyloxy)-3-phenylprop-2-ene
282716-03-4

1-(4-methoxybenzyloxy)-3-phenylprop-2-ene

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With trichlorophosphate In 1,2-dichloro-ethane at 20℃; for 0.833333h;90%
With silver hexafluoroantimonate; 1,2,3-trimethoxybenzene In dichloromethane at 40℃; for 2h;2%
(E)-1-tert-butyldimethylsilyloxy-3-phenyl-2-propene
100009-29-8

(E)-1-tert-butyldimethylsilyloxy-3-phenyl-2-propene

CsCO3

CsCO3

3-Phenylpropenol
104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
In water; N,N-dimethyl-formamide at 100℃; for 3h;89%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

3-Phenyl-1-propanol
122-97-4

3-Phenyl-1-propanol

Conditions
ConditionsYield
With hydrogen In ethanol at 20℃; under 760.051 Torr; for 2h; chemoselective reaction;100%
With hydrogen In water at 20℃; under 760.051 Torr; for 2h; Sealed tube;100%
With hydrogen In ethanol at 100℃; under 30003 Torr; Flow reactor; Green chemistry; chemoselective reaction;100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

Cinnamyl bromide
4392-24-9

Cinnamyl bromide

Conditions
ConditionsYield
With 1,1,1,2,2,2-hexamethyldisilane; pyridinium hydrobromide perbromide In chloroform at 25℃; for 0.5h;100%
With chloro-trimethyl-silane; lithium bromide In acetonitrile for 12h; Heating;93%
With carbon tetrabromide; polystyrene-supported triphenylphosphine In chloroform at 20℃; for 0.166667h;89%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

3-phenyl-propenal
104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With dimethyl selenoxide In dichloromethane for 7h; Heating;100%
With 2,2'-bipyridylchromium peroxide In benzene for 1.25h; Heating;100%
With tert.-butylhydroperoxide; polystyrene-bound phenylselenic acid In tetrachloromethane for 63h; Heating;100%
Dimethoxymethane
109-87-5

Dimethoxymethane

3-Phenylpropenol
104-54-1

3-Phenylpropenol

γ-Phenyl-allylalkohol-methoxy-methylether
88738-40-3, 91970-13-7

γ-Phenyl-allylalkohol-methoxy-methylether

Conditions
ConditionsYield
With toluene-4-sulfonic acid; lithium bromide for 0.75h; Ambient temperature;100%
With 12-tungstophosphoric acid immobilized on [bmim][FeCl4] at 75 - 82℃; for 0.00555556h; Microwave irradiation;98%
With 1-butyl-3-methylimidazolium tetrachloroindate for 0.025h; Microwave irradiation; chemoselective reaction;97%
With tin(IV)octabromotetraphenylporphyrinato trifluoromethanesulfonate at 20℃; for 0.0833333h;95%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

3-phenyl-propionaldehyde
104-53-0

3-phenyl-propionaldehyde

Conditions
ConditionsYield
With Ir(ClO4)(CO)(PPh3)2; hydrogen In chloroform-d1 at 25℃; under 760 Torr; for 3h;100%
With (1,5-cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; hydrogen In tetrahydrofuran at 23℃; for 1h;100%
With 20 % Pd(OH)2/C; hydrogen In benzene at 20℃; Inert atmosphere;92%
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

3-Phenylpropenol
104-54-1

3-Phenylpropenol

A

methanol
67-56-1

methanol

B

cinnamyl benzoate
5320-75-2

cinnamyl benzoate

Conditions
ConditionsYield
2[{Cl(C6F13CH2CH2)2SnOSn(CH2CH2C6F13)2Cl}2] In various solvent(s) at 150℃; for 16h;A n/a
B 100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

benzoic acid ethyl ester
93-89-0

benzoic acid ethyl ester

A

ethanol
64-17-5

ethanol

B

cinnamyl benzoate
5320-75-2

cinnamyl benzoate

Conditions
ConditionsYield
2[{Cl(C6F13CH2CH2)2SnOSn(CH2CH2C6F13)2Cl}2] In various solvent(s) at 150℃; for 16h;A n/a
B 100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

3-phenylpropanoic acid methyl ester
103-25-3

3-phenylpropanoic acid methyl ester

A

methanol
67-56-1

methanol

B

3-phenyl-2-propenyl benzenepropanoate
140671-25-6, 28048-98-8

3-phenyl-2-propenyl benzenepropanoate

Conditions
ConditionsYield
2[{Cl(C6F13CH2CH2)2SnOSn(CH2CH2C6F13)2Cl}2] In various solvent(s) at 150℃; for 16h;A n/a
B 100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

ethyl dihydrocinnamate
2021-28-5

ethyl dihydrocinnamate

A

ethanol
64-17-5

ethanol

B

3-phenyl-2-propenyl benzenepropanoate
140671-25-6, 28048-98-8

3-phenyl-2-propenyl benzenepropanoate

Conditions
ConditionsYield
2[{Cl(C6F13CH2CH2)2SnOSn(CH2CH2C6F13)2Cl}2] In various solvent(s) at 150℃; for 16h;A n/a
B 100%
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

3-Phenylpropenol
104-54-1

3-Phenylpropenol

cinnamyl benzoate
5320-75-2

cinnamyl benzoate

Conditions
ConditionsYield
[Cl(C6F13C2H4)2SnOSn(C2H4C6F13)2Cl]2 In various solvent(s) at 150℃; for 16h;100%
With iron(III)-acetylacetonate In n-heptane at 105℃; for 20h; Inert atmosphere;96%
ethyl 3-phenyl-2-propenoate
103-36-6

ethyl 3-phenyl-2-propenoate

3-Phenylpropenol
104-54-1

3-Phenylpropenol

3-phenyl-2-propen-1-yl 3-phenylacrylate
40918-97-6, 61019-10-1, 122-69-0

3-phenyl-2-propen-1-yl 3-phenylacrylate

Conditions
ConditionsYield
[Cl(C6F13C2H4)2SnOSn(C2H4C6F13)2Cl]2 In toluene at 150℃; for 16h;100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

benzoic acid ethyl ester
93-89-0

benzoic acid ethyl ester

cinnamyl benzoate
5320-75-2

cinnamyl benzoate

Conditions
ConditionsYield
[Cl(C6F13C2H4)2SnOSn(C2H4C6F13)2Cl]2 In various solvent(s) at 150℃; for 16h;100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

3-phenylpropanoic acid methyl ester
103-25-3

3-phenylpropanoic acid methyl ester

3-phenyl-2-propenyl benzenepropanoate
140671-25-6, 28048-98-8

3-phenyl-2-propenyl benzenepropanoate

Conditions
ConditionsYield
[Cl(C6F13C2H4)2SnOSn(C2H4C6F13)2Cl]2 In various solvent(s) at 150℃; for 16h;100%
With zinc diacetate In toluene for 18h; Reflux;
3-Phenylpropenol
104-54-1

3-Phenylpropenol

ethyl dihydrocinnamate
2021-28-5

ethyl dihydrocinnamate

3-phenyl-2-propenyl benzenepropanoate
140671-25-6, 28048-98-8

3-phenyl-2-propenyl benzenepropanoate

Conditions
ConditionsYield
[Cl(C6F13C2H4)2SnOSn(C2H4C6F13)2Cl]2 In various solvent(s) at 150℃; for 16h;100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

bis-cinnamyl-phosphinic acid

bis-cinnamyl-phosphinic acid

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); hypophosphorous acid; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tert-Amyl alcohol at 102℃; for 24h; Molecular sieve; Inert atmosphere;100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

phenylphosphinic acid
1779-48-2

phenylphosphinic acid

cinnamyl(phenyl)phosphonic acid

cinnamyl(phenyl)phosphonic acid

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tert-Amyl alcohol at 102℃; for 24h; Inert atmosphere;100%
With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,2-dimethoxyethane; N,N-dimethyl-formamide at 115℃; for 24h;87%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

N-phenyl-benzimidoyl chloride
4903-36-0

N-phenyl-benzimidoyl chloride

3-phenylallyl (N-phenyl)benzimidate

3-phenylallyl (N-phenyl)benzimidate

Conditions
ConditionsYield
Stage #1: 3-Phenylpropenol With sodium hydride In tetrahydrofuran; mineral oil at 0 - 30℃; for 1.25h;
Stage #2: N-phenyl-benzimidoyl chloride In tetrahydrofuran; mineral oil at 0 - 20℃; for 20h;
100%
Stage #1: 3-Phenylpropenol With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 2h;
Stage #2: N-phenyl-benzimidoyl chloride In tetrahydrofuran; mineral oil for 2h;
Stage #3: With tert-butyl methyl ether In tetrahydrofuran; water; mineral oil
2-bromoisobutyric acid bromide
20769-85-1

2-bromoisobutyric acid bromide

3-Phenylpropenol
104-54-1

3-Phenylpropenol

cinnamyl 2-bromo-2-methylpropanoate
60533-00-8

cinnamyl 2-bromo-2-methylpropanoate

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 0℃; for 1.5h; Inert atmosphere;100%
Stage #1: 3-Phenylpropenol With sodium hydride In dichloromethane; mineral oil at 20℃; for 0.166667h;
Stage #2: 2-bromoisobutyric acid bromide In dichloromethane; mineral oil at 20℃;
3-Phenylpropenol
104-54-1

3-Phenylpropenol

anthranilic acid
118-92-3

anthranilic acid

2-(cinnamylamino)benzoic acid
99753-82-9

2-(cinnamylamino)benzoic acid

Conditions
ConditionsYield
With palladium diacetate; sodium 3-(diphenylphosphanyl)benzenesulfonate In water at 70℃; stereoselective reaction;100%
diiodomethane
75-11-6

diiodomethane

3-Phenylpropenol
104-54-1

3-Phenylpropenol

(trans)-(2-phenylcyclopropyl)methanol

(trans)-(2-phenylcyclopropyl)methanol

Conditions
ConditionsYield
With diethylzinc In hexane; dichloromethane at 0 - 20℃; for 18.5h;100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

butyl cinnamyl-H-phosphinate
1012339-08-0

butyl cinnamyl-H-phosphinate

butyl bis cinnamylphosphinate

butyl bis cinnamylphosphinate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tert-Amyl alcohol for 24h; Reflux; Inert atmosphere; Dean-Stark;100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

butyl (2-ethylphthalimide)-H-phosphinate

butyl (2-ethylphthalimide)-H-phosphinate

butyl (2-ethylphthalimide)cinnamylphosphinate

butyl (2-ethylphthalimide)cinnamylphosphinate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tert-Amyl alcohol for 24h; Reflux; Inert atmosphere; Dean-Stark;100%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

acetic anhydride
108-24-7

acetic anhydride

cinnamyl acetate
103-54-8

cinnamyl acetate

Conditions
ConditionsYield
With Cp2Ti(OSO2C8F17)2 at 20℃; for 0.0833333h; Neat (no solvent);99%
With pyridine In dichloromethane at 20℃; for 24h; Inert atmosphere;99%
cerium triflate In acetonitrile at 20℃; for 2.5h;98%
3-Phenylpropenol
104-54-1

3-Phenylpropenol

benzoyl chloride
98-88-4

benzoyl chloride

cinnamyl benzoate
5320-75-2

cinnamyl benzoate

Conditions
ConditionsYield
Stage #1: 3-Phenylpropenol With dmap; triethylamine In dichloromethane at 0℃; for 0.166667h; Inert atmosphere;
Stage #2: benzoyl chloride In dichloromethane for 15h; Inert atmosphere;
99%
Stage #1: 3-Phenylpropenol With pyridine; dmap In dichloromethane at 5℃; for 0.166667h; Inert atmosphere; Sealed tube;
Stage #2: benzoyl chloride In dichloromethane at 5 - 20℃; for 16h; Inert atmosphere; Sealed tube;
89%
With samarium In acetonitrile at 70℃; for 0.05h;77%
trimethylsilylazide
4648-54-8

trimethylsilylazide

3-Phenylpropenol
104-54-1

3-Phenylpropenol

trimethylsilyl cinnamyl ether
109283-53-6, 141427-94-3, 18042-41-6

trimethylsilyl cinnamyl ether

Conditions
ConditionsYield
In tetrahydrofuran for 0.5h; Ambient temperature;99%

104-54-1Related news

On the role of water in selective hydrogenation of cinnamaldehyde to Cinnamyl alcohol (cas 104-54-1) on PtFe catalysts08/15/2019

A series of carbon nanotube (CNT)-supported bimetallic PtFe nanoparticles were synthesized and employed as catalysts for hydrogenation of cinnamaldehyde in pure water. A synergy between water and bimetallic PtFe catalysts has allowed the efficiently selective production of cinnamyl alcohol. With...detailed

Overexpression of Sedum alfredii Cinnamyl alcohol (cas 104-54-1) dehydrogenase increases the tolerance and accumulation of cadmium in Arabidopsis08/14/2019

Plant cell walls protect plants from heavy metal stress by resistance, transport and the adsorption process. Cell walls are impregnated with lignin, which enables structural integrity, long-distance water transport and protects plants from many types of stress. Cinnamyl alcohol dehydrogenase (CA...detailed

Constructing surface synergistic effect in Cu-Cu2O hybrids and monolayer H1.4Ti1.65O4·H2O nanosheets for selective Cinnamyl alcohol (cas 104-54-1) oxidation to cinnamaldehyde☆08/13/2019

A multifunctional photocatalyst is constructed based on Cu-Cu2O hybrid and monolayer H1.4Ti1.65O4·H2O nanosheets via an in situ photo-deposition process (Cu-Cu2O/TNS). The prepared sample enables the oxidation of cinnamyl alcohol to cinnamaldehyde with over 95% of selectivity under visible ligh...detailed

Selective hydrogenation of cinnamaldehyde to Cinnamyl alcohol (cas 104-54-1) over BN-supported Pt catalysts at room temperature08/12/2019

BN-supported Pt catalysts were prepared by an impregnation method using Pt(NH3)4(NO3)2 as metal precursors and tested in the liquid-phase selective hydrogenation of cinnamaldehyde. It was found that the Pt/BN catalyst exhibited a high performance for the selective CO hydrogenation at room temper...detailed

Water-enhanced selective hydrogenation of cinnamaldehyde to Cinnamyl alcohol (cas 104-54-1) on RuSnB/CeO2 catalysts08/11/2019

The CeO2-supported ternary RuSnB catalysts were synthesized by incipient wetness impregnation procedures and applied in hydrogenation of cinnamaldehyde in pure water as the solvent. A synergy effect between Ru-based catalysts and water molecules has afforded the efficiently selective transformat...detailed

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