13-(4-Nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane

Base Information

• Chemical Name: 13-(4-Nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane
• CAS No.: 66750-07-0
• Molecular Formula: C16H24N2O5
• Molecular Weight: 324.377
• DSSTox Substance ID: DTXSID20498763
• Wikidata: Q82349028
• Mol file: 66750-07-0.mol

Synonyms:66750-07-0;DTXSID20498763;13-(4-Nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane

Chemical Property of 13-(4-Nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane

Chemical Property:

• XLogP3: 0.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 7
• Rotatable Bond Count: 1
• Exact Mass: 324.16852187
• Heavy Atom Count: 23
• Complexity: 295

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1COCCOCCOCCOCCN1C2=CC=C(C=C2)N=O

Technology Process of 13-(4-Nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane

There total 2 articles about 13-(4-Nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

13-phenyl-1,4,7,10-tetraoxa-13-aza-cyclopentadecane (66750-10-5) → 13-(4-nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane (66750-07-0)

Guidance literature:

With hydrogenchloride; sodium nitrite; In water; for 20h; temp. below 5 deg C;

Reference yield:

2,2'-(phenylimino)bis[ethanol] (120-07-0) → 13-(4-nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane (66750-07-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 16 percent / NaOH / dioxane / 30 h / Heating

2: 83 percent / 37percent HCl, NaNO₂ / H₂O / 20 h / temp. below 5 deg C

With hydrogenchloride; sodium hydroxide; sodium nitrite; In 1,4-dioxane; water;

Reference yield: 87.0%

13-(4-nitrosophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane (66750-07-0) → N-(4-aminophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane (66750-05-8)

Guidance literature:

With hydrogenchloride; tin(ll) chloride; In water; at 40 ℃; for 0.333333h;

upstream raw materials:

13-phenyl-1,4,7,10-tetraoxa-13-aza-cyclopentadecane

2,2'-(phenylimino)bis[ethanol]

Downstream raw materials:

N-(4-aminophenyl)-1,4,7,10-tetraoxa-13-azacyclopentadecane

Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen

Bis<4-(4,7,10,13-tetraoxa-1-azacyclopentadecyl)phenyl>diazen-N-oxid

1,4,7,10-tetraoxa-15-azacyclopentadecane