ETHYL 2-FURYLCARBAMATE

Base Information

• Chemical Name: ETHYL 2-FURYLCARBAMATE
• CAS No.: 54915-62-7
• Molecular Formula: C7H9 N O3
• Molecular Weight: 155.15126
• Hs Code.: 2932190090
• Mol file: 54915-62-7.mol

Synonyms:2-Furancarbamicacid, ethyl ester (7CI); Carbamic acid, 2-furanyl-, ethyl ester (9CI);(2-Furanyl)carbamic acid ethyl ester; Ethyl N-(2-furyl)carbamate

Chemical Property of ETHYL 2-FURYLCARBAMATE

Chemical Property:

• Vapor Pressure: 1.15mmHg at 25°C
• Melting Point: 27-28 °C
• Boiling Point: 175.3°C at 760 mmHg
• PKA: 13.38±0.70(Predicted)
• Flash Point: 59.8°C
• PSA: 51.47000
• Density: 1.21g/cm³
• LogP: 1.92100

Purity/Quality:

97% ^*data from raw suppliers

ETHYL-2-FURYLCARBAMATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ETHYL 2-FURYLCARBAMATE

There total 2 articles about ETHYL 2-FURYLCARBAMATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

ethanol (64-17-5) + 2-furoyl azide (20762-98-5) → furan-2-yl carbamic acid ethyl ester (54915-62-7)

Guidance literature:

for 12h; Heating;

DOI:10.1021/jo982061+

Reference yield: 70.0%

2-furanoic acid (88-14-2) + ethanol (64-17-5) → furan-2-yl carbamic acid ethyl ester (54915-62-7)

Guidance literature:

2-furanoic acid; With thionyl chloride; at 100 ℃; for 5h;

With sodium azide; cetyltrimethylammonim bromide; In dichloromethane; at 20 ℃; for 18h;

ethanol; at 80 ℃; for 4h; Further stages.;

DOI:10.1055/s-2007-990947

Reference yield: 66.0%

furan-2-yl carbamic acid ethyl ester (54915-62-7) + 3-(2-azidophenyl)but-3-en-1-ol → ethyl 3-(2-azidophenyl)but-3-enoyl(furan-2-yl)carbamate (1170694-14-0)

Guidance literature:

furan-2-yl carbamic acid ethyl ester; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.75h; Inert atmosphere;

3-(2-azidophenyl)but-3-en-1-ol; In tetrahydrofuran; hexane; at 0 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/acs.joc.6b00771

upstream raw materials:

ethanol

2-furoyl azide

2-furanoic acid

Downstream raw materials:

[3-(3,4-dimethoxyphenyl)-but-3-enyl]furan-2-yl-carbamic acid ethyl ester

ethyl 2-furyl(2-iodobenzyl)carbamate

ethyl (2-acetylphenyl)(furan-2-yl)carbamate

ethyl 3-(2-bromophenyl)but-3-enoyl(furan-2-yl)carbamate