2-(Vinyloxy)ethyl methacrylate

Base Information

• Chemical Name: 2-(Vinyloxy)ethyl methacrylate
• CAS No.: 1464-69-3
• Molecular Formula: C8H12 O3
• Molecular Weight: 156.181
• Hs Code.: 2916140000
• European Community (EC) Number: 215-980-7
• DSSTox Substance ID: DTXSID00883678
• Nikkaji Number: J206.669F
• Wikidata: Q82862549
• Mol file: 1464-69-3.mol

Synonyms:vinyloxyethylmethacrylate;VOEMA

Chemical Property of 2-(Vinyloxy)ethyl methacrylate

Chemical Property:

• Vapor Pressure: 0.265mmHg at 25°C
• Refractive Index: 1.4430 (estimate)
• Boiling Point: 204.4°C at 760 mmHg
• Flash Point: 76.7°C
• PSA: 35.53000
• Density: 0.973g/cm³
• LogP: 1.26580
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 156.078644241
• Heavy Atom Count: 11
• Complexity: 161

Purity/Quality:

99%, ^*data from raw suppliers

2-(VINYLOXY)ETHYL METHACRYLATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCCOC=C

Technology Process of 2-(Vinyloxy)ethyl methacrylate

There total 4 articles about 2-(Vinyloxy)ethyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

ethyleneglycol vinyl ether (764-48-7) + Methacryloyl chloride (920-46-7,26937-45-1) → 2-(vinyloxy)ethyl methacrylate (1464-69-3)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 4.5h; Inert atmosphere;

DOI:10.1021/acs.biomac.8b01001

Reference yield:

ethyleneglycol vinyl ether (764-48-7) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → 2-(vinyloxy)ethyl methacrylate (1464-69-3)

Guidance literature:

With sodium 2-vinyloxyethoxide; N-Phenyl-2-naphthylamine; hydroquinone; at 95 ℃; for 4h; Product distribution; other basic reagents;

Reference yield:

ethyleneglycol vinyl ether (764-48-7) + 2-methyl-butyl acrylate (97-88-1,9003-63-8) → 2-(vinyloxy)ethyl methacrylate (1464-69-3)

Guidance literature:

With methanol; sodium methylate;

upstream raw materials:

ethyleneglycol vinyl ether

methacrylic acid methyl ester

2-methyl-butyl acrylate

Methacryloyl chloride

Downstream raw materials:

1,1-dimethoxyethane

Refernces

• 1、 Haas,Simon. "-". . p. 421. Retrieved 1957.
• 2、 -. "Acid-responsive cross-linked polymer prodrug, and preparation method and application thereof". Paragraph 0068-0072. . Retrieved 2020/07/15.