[1,1'-Biphenyl]-4-amine, N,N-diphenyl-4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-

Base Information

Chemical Name:[1,1'-Biphenyl]-4-amine, N,N-diphenyl-4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
CAS No.:675571-82-1
Molecular Formula:C30H30BNO2
Molecular Weight:447.385
Hs Code.:

Synonyms:N,N-diphenyl-4′-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1'-biphenyl]-4-amine;

Suppliers and Price of [1,1'-Biphenyl]-4-amine, N,N-diphenyl-4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 10 raw suppliers

Chemical Property of [1,1'-Biphenyl]-4-amine, N,N-diphenyl-4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-

Chemical Property:

PSA：21.70000
LogP:7.12260

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of [1,1'-Biphenyl]-4-amine, N,N-diphenyl-4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-

There total 12 articles about [1,1'-Biphenyl]-4-amine, N,N-diphenyl-4'-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.6%

: 73183-34-3
bis(pinacol)diborane

: 202831-65-0
(4'-bromobiphenyl-4-yl)-diphenylamine

: 675571-82-1
N,N-diphenyl-4’-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1’-biphenyl]-4-amine

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; at 100 ℃; Inert atmosphere;

Reference yield: 74.0%

: 675571-82-1
N,N-diphenyl-4’-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1’-biphenyl]-4-amine

Guidance literature:: With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; at 95 ℃; for 24h;

Reference yield:

: 589-87-7
1,4-bromoiodobenzene

: 956-24-1
1-[bis(dimethylamino)methylidene]-3-phenylurea

: 40230-97-5
N,N-dimethyl-4-[(trimethylsilyl)ethynyl]aniline

: ((±)-trans)-3-(piperazin-1-yl)-1,2,3,4-tetrahydronaphthalen-2-ol

: 10456-04-9
11C-carbon monooxide

: 2-(prop-2-ynyloxymethyl)aniline

: 675571-82-1
N,N-diphenyl-4’-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-[1,1’-biphenyl]-4-amine

: 3-[bis(dimethylamino)methylidene]-1-(4-bromophenyl)-1-phenylurea

: 4-[(4-bromophenyl)ethynyl]-N,N-dimethylaniline

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate; 18-crown-6 ether; copper / N,N-dimethyl-formamide / Reflux

2: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triphenylphosphine; triethylamine / Reflux

3: potassium carbonate / methanol; tetrahydrofuran / 20 °C

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; 18-crown-6 ether; copper; potassium carbonate; triethylamine; triphenylphosphine; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1039/c4dt01397b