1,3-Dioxane, 4-[[(4R,6R)-6-[(2S)-2-[(4-methoxyphenyl)methoxy]-3-butynyl]-2,2-dimeth yl-1,3-dioxan-4-yl]methyl]-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-, (4R,6R)-

Base Information

Chemical Name:1,3-Dioxane, 4-[[(4R,6R)-6-[(2S)-2-[(4-methoxyphenyl)methoxy]-3-butynyl]-2,2-dimeth yl-1,3-dioxan-4-yl]methyl]-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-, (4R,6R)-
CAS No.:676549-15-8
Molecular Formula:C41H58O8
Molecular Weight:678.907
Hs Code.:

1,3-Dioxane,
4-[[(4R,6R)-6-[(2S)-2-[(4-methoxyphenyl)methoxy]-3-butynyl]-2,2-dimeth
yl-1,3-dioxan-4-yl]methyl]-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]-
3,5-dimethyl-1-hexenyl]-2,2-dimethyl-, (4R,6R)-

Synonyms:

Suppliers and Price of 1,3-Dioxane, 4-[[(4R,6R)-6-[(2S)-2-[(4-methoxyphenyl)methoxy]-3-butynyl]-2,2-dimeth yl-1,3-dioxan-4-yl]methyl]-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-, (4R,6R)-

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Chemical Property of 1,3-Dioxane, 4-[[(4R,6R)-6-[(2S)-2-[(4-methoxyphenyl)methoxy]-3-butynyl]-2,2-dimeth yl-1,3-dioxan-4-yl]methyl]-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-, (4R,6R)-

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Technology Process of 1,3-Dioxane, 4-[[(4R,6R)-6-[(2S)-2-[(4-methoxyphenyl)methoxy]-3-butynyl]-2,2-dimeth yl-1,3-dioxan-4-yl]methyl]-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-, (4R,6R)-

There total 11 articles about 1,3-Dioxane, 4-[[(4R,6R)-6-[(2S)-2-[(4-methoxyphenyl)methoxy]-3-butynyl]-2,2-dimeth yl-1,3-dioxan-4-yl]methyl]-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-, (4R,6R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 323192-62-7
(4S,5S)-4,6-dimethyl-5-(p-methoxybenzyloxy)-trans-hept-2-enal

: 676549-15-8
C₄₁H₅₈O₈

Guidance literature:: Multi-step reaction with 8 steps

1.1: K₂CO₃; MeOH / 3 h / 20 °C

2.1: 2.22 g / TsOH*H₂O; 3 Angstroem molecular sieves / 17 h / 20 °C

3.1: n-BuLi / tetrahydrofuran; hexane / 2.5 h / -60 - -40 °C

3.2: BF₃*Et₂O / tetrahydrofuran; hexane / 0.25 h / -78 °C

3.3: 82 percent / tetrahydrofuran; hexane / 1.5 h / -78 °C

4.1: 15 h / 100 °C

5.1: Pt(DVDS) / tetrahydrofuran; xylene / 21 h / 20 °C

6.1: 545 mg / TsOH*H₂O; 3 Angstroem molecular sieves / 21 h / 20 °C

With methanol; n-butyllithium; bis(η2:η2-1,3-divinyltetramethyl)platinum(0); 3 A molecular sieve; potassium carbonate; toluene-4-sulfonic acid; In tetrahydrofuran; hexane; xylene;
DOI:10.1021/ja039618+

Reference yield:

: 676548-69-9
(3S,4S)-2,4-dimethyl-3-(p-methoxybenzyloxy)-5-hexene

: 676549-15-8
C₄₁H₅₈O₈

Guidance literature:: Multi-step reaction with 11 steps

1.1: 58 percent / (4,5-dihydrolMes)Cl₂Ru=CH-(o-OiPr)C₆H₄ / CH₂Cl₂ / 53 h

2.1: 91 percent / DIBAL-H / CH₂Cl₂ / 0.5 h / -78 °C

3.1: 89 percent / SO₃*pyridine; Et₃N; DMSO / CH₂Cl₂ / 4 h / 20 °C

4.1: K₂CO₃; MeOH / 3 h / 20 °C

5.1: 2.22 g / TsOH*H₂O; 3 Angstroem molecular sieves / 17 h / 20 °C

6.1: n-BuLi / tetrahydrofuran; hexane / 2.5 h / -60 - -40 °C

6.2: BF₃*Et₂O / tetrahydrofuran; hexane / 0.25 h / -78 °C

6.3: 82 percent / tetrahydrofuran; hexane / 1.5 h / -78 °C

7.1: 15 h / 100 °C

8.1: Pt(DVDS) / tetrahydrofuran; xylene / 21 h / 20 °C

9.1: 545 mg / TsOH*H₂O; 3 Angstroem molecular sieves / 21 h / 20 °C

With methanol; n-butyllithium; bis(η2:η2-1,3-divinyltetramethyl)platinum(0); pyridine-SO₃ complex; (4,5-dihydrolMes)Cl₂Ru=CH-(o-OiPr)C₆H₄; 3 A molecular sieve; diisobutylaluminium hydride; potassium carbonate; toluene-4-sulfonic acid; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; hexane; dichloromethane; xylene;
DOI:10.1021/ja039618+

Reference yield:

: 676549-52-3
(4S,5S)-4,6-dimethyl-5-(p-methoxybenzyloxy)-trans-hept-2-en-1-ol

: 676549-15-8
C₄₁H₅₈O₈

Guidance literature:: Multi-step reaction with 9 steps

1.1: 89 percent / SO₃*pyridine; Et₃N; DMSO / CH₂Cl₂ / 4 h / 20 °C

2.1: K₂CO₃; MeOH / 3 h / 20 °C

3.1: 2.22 g / TsOH*H₂O; 3 Angstroem molecular sieves / 17 h / 20 °C

4.1: n-BuLi / tetrahydrofuran; hexane / 2.5 h / -60 - -40 °C

4.2: BF₃*Et₂O / tetrahydrofuran; hexane / 0.25 h / -78 °C

4.3: 82 percent / tetrahydrofuran; hexane / 1.5 h / -78 °C

5.1: 15 h / 100 °C

6.1: Pt(DVDS) / tetrahydrofuran; xylene / 21 h / 20 °C

7.1: 545 mg / TsOH*H₂O; 3 Angstroem molecular sieves / 21 h / 20 °C

With methanol; n-butyllithium; bis(η2:η2-1,3-divinyltetramethyl)platinum(0); pyridine-SO₃ complex; 3 A molecular sieve; potassium carbonate; toluene-4-sulfonic acid; dimethyl sulfoxide; triethylamine; In tetrahydrofuran; hexane; dichloromethane; xylene;
DOI:10.1021/ja039618+