Silane, [(4S,6R,10S)-6-[(dimethylsilyl)oxy]-4,10-bis[(4-methoxyphenyl)methoxy] -11-[(4R,6R)-6-[[(4R,6R)-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]-2,2-dimeth yl-1,3-dioxan-4-yl]-1,8-undecadiynyl]trimethyl-

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Chemical Name:Silane, [(4S,6R,10S)-6-[(dimethylsilyl)oxy]-4,10-bis[(4-methoxyphenyl)methoxy] -11-[(4R,6R)-6-[[(4R,6R)-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]-2,2-dimeth yl-1,3-dioxan-4-yl]-1,8-undecadiynyl]trimethyl-
CAS No.:676549-65-8
Molecular Formula:C61H90O11Si2
Molecular Weight:1055.55
Hs Code.:

Silane,
[(4S,6R,10S)-6-[(dimethylsilyl)oxy]-4,10-bis[(4-methoxyphenyl)methoxy]
-11-[(4R,6R)-6-[[(4R,6R)-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]-
3,5-dimethyl-1-hexenyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]-2,2-dimeth
yl-1,3-dioxan-4-yl]-1,8-undecadiynyl]trimethyl-

Synonyms:

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Chemical Property of Silane, [(4S,6R,10S)-6-[(dimethylsilyl)oxy]-4,10-bis[(4-methoxyphenyl)methoxy] -11-[(4R,6R)-6-[[(4R,6R)-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]-2,2-dimeth yl-1,3-dioxan-4-yl]-1,8-undecadiynyl]trimethyl-

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Technology Process of Silane, [(4S,6R,10S)-6-[(dimethylsilyl)oxy]-4,10-bis[(4-methoxyphenyl)methoxy] -11-[(4R,6R)-6-[[(4R,6R)-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]-2,2-dimeth yl-1,3-dioxan-4-yl]-1,8-undecadiynyl]trimethyl-

There total 21 articles about Silane, [(4S,6R,10S)-6-[(dimethylsilyl)oxy]-4,10-bis[(4-methoxyphenyl)methoxy] -11-[(4R,6R)-6-[[(4R,6R)-6-[(1E,3S,4S)-4-[(4-methoxyphenyl)methoxy]- 3,5-dimethyl-1-hexenyl]-2,2-dimethyl-1,3-dioxan-4-yl]methyl]-2,2-dimeth yl-1,3-dioxan-4-yl]-1,8-undecadiynyl]trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 77-76-9
2,2-dimethoxy-propane

: 676549-65-8
C₆₁H₉₀O₁₁Si₂

Guidance literature:: Multi-step reaction with 3 steps

1.1: 545 mg / TsOH*H₂O; 3 Angstroem molecular sieves / 21 h / 20 °C

2.1: n-BuLi / tetrahydrofuran; hexane / 2.5 h / -78 - -40 °C

2.2: Bf₃*Et₂O / tetrahydrofuran; hexane / 0.17 h / -78 °C

2.3: 59 percent / tetrahydrofuran; hexane / 3 h / -78 °C

3.1: 100 °C

With n-butyllithium; 3 A molecular sieve; toluene-4-sulfonic acid; In tetrahydrofuran; hexane;
DOI:10.1021/ja039618+

Reference yield:

: 197899-19-7
(2R)-1-chloro-2-hydroxy-4-pentene

: 676549-65-8
C₆₁H₉₀O₁₁Si₂

Guidance literature:: Multi-step reaction with 8 steps

1.1: 81 percent / KOH

2.1: n-BuLi / tetrahydrofuran / -78 - 20 °C

2.2: BF₃*Et₂O / tetrahydrofuran / 0.33 h / -78 °C

2.3: 75 percent / tetrahydrofuran / 1 h / -78 °C

3.1: 77 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 20 °C

4.1: NaH / dimethylformamide / 0.17 h

4.2: 73 percent / Bu₄NI / dimethylformamide / 25 h / 20 °C

5.1: n-BuLi / tetrahydrofuran / 0.17 h / -50 °C

5.2: 434 mg / tetrahydrofuran / 0.5 h / -40 °C

6.1: 32 percent / (S,S)-salen Co(III)OAc; H₂O / tetrahydrofuran / 1 h

7.1: n-BuLi / tetrahydrofuran; hexane / 2.5 h / -78 - -40 °C

7.2: Bf₃*Et₂O / tetrahydrofuran; hexane / 0.17 h / -78 °C

7.3: 59 percent / tetrahydrofuran; hexane / 3 h / -78 °C

8.1: 100 °C

With potassium hydroxide; n-butyllithium; (S,S)-salen Co(III)OAc; water; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja039618+

Reference yield:

: 144422-60-6
(R)-2-but-3-enyloxirane

: 676549-65-8
C₆₁H₉₀O₁₁Si₂

Guidance literature:: Multi-step reaction with 7 steps

1.1: n-BuLi / tetrahydrofuran / -78 - 20 °C

1.2: BF₃*Et₂O / tetrahydrofuran / 0.33 h / -78 °C

1.3: 75 percent / tetrahydrofuran / 1 h / -78 °C

2.1: 77 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 20 °C

3.1: NaH / dimethylformamide / 0.17 h

3.2: 73 percent / Bu₄NI / dimethylformamide / 25 h / 20 °C

4.1: n-BuLi / tetrahydrofuran / 0.17 h / -50 °C

4.2: 434 mg / tetrahydrofuran / 0.5 h / -40 °C

5.1: 32 percent / (S,S)-salen Co(III)OAc; H₂O / tetrahydrofuran / 1 h

6.1: n-BuLi / tetrahydrofuran; hexane / 2.5 h / -78 - -40 °C

6.2: Bf₃*Et₂O / tetrahydrofuran; hexane / 0.17 h / -78 °C

6.3: 59 percent / tetrahydrofuran; hexane / 3 h / -78 °C

7.1: 100 °C

With n-butyllithium; (S,S)-salen Co(III)OAc; water; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja039618+